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Covalent–Organic Frameworks: Advanced Organic Electrode Materials for Rechargeable Batteries
Authors:Tao Sun  Jian Xie  Wei Guo  Dong‐Sheng Li  Qichun Zhang
Abstract:Covalent–organic frameworks (COFs), featuring structural diversity, framework tunability and functional versatility, have emerged as promising organic electrode materials for rechargeable batteries and garnered tremendous attention in recent years. The adjustable pore configuration, coupled with the functionalization of frameworks through pre‐ and post‐synthesis strategies, enables a precise customization of COFs, which provides a novel perspective to deepen the understanding of the fundamental problems of organic electrode materials. In this review, a summary of the recent research into COFs electrode materials for rechargeable batteries including lithium‐ion batteries, sodium‐ion batteries, potassium‐ion batteries, and aqueous zinc batteries is provided. In addition, this review will also cover the working principles, advantages and challenges, strategies to improve electrochemical performance, and applications of COFs in rechargeable batteries.
Keywords:aqueous zinc batteries  covalent–  organic frameworks  lithium‐ion batteries (LIBs)  potassium‐ion batteries  rechargeable batteries  sodium‐ion batteries
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