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Synthesis of new 2-C-(2,3:5,6-di-O-isopropylidene)-beta-D-mannofuranosyldithioacetate derivatives
Authors:Dominguez Zaira J  Marchand Patrice  Gulea Mihaela  Masson Serge
Institution:Unidad de Servicios de Apoyo en Resoluciòn Analitica, Universidad Veracruzana. Xalapa Ver., Mexico.
Abstract:Various new C-glycosides have been synthesized through the thioacylation reaction of different amines by a 2-C-mannofuranosyldithioacetate. Amino acids, di- and polyamines (putresceine, spermine, spermidine) and one amino alcohol were in particular used to generate glycothiopeptidic or precursors of "bola" structures.
Keywords:Dithioesters  C-Glycosides  Thioacylation  Polyamines  Amino acids
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