Synthesis of new 2-C-(2,3:5,6-di-O-isopropylidene)-beta-D-mannofuranosyldithioacetate derivatives |
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Authors: | Dominguez Zaira J Marchand Patrice Gulea Mihaela Masson Serge |
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Institution: | Unidad de Servicios de Apoyo en Resoluciòn Analitica, Universidad Veracruzana. Xalapa Ver., Mexico. |
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Abstract: | Various new C-glycosides have been synthesized through the thioacylation reaction of different amines by a 2-C-mannofuranosyldithioacetate. Amino acids, di- and polyamines (putresceine, spermine, spermidine) and one amino alcohol were in particular used to generate glycothiopeptidic or precursors of "bola" structures. |
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Keywords: | Dithioesters C-Glycosides Thioacylation Polyamines Amino acids |
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