The interaction of sugars with borate: an n.m.r. spectroscopic study |
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| Authors: | G.R. Kennedy M.J. How |
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| Affiliation: | Department of Chemistry, University of Birmingham, P.O. Box 363, Birmingham B15 2TT Great Britain |
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| Abstract: | 11B n.m.r. spectroscopy studies of solutions of sugars in the presence of borax have shown the existence of boron-containing complexes. Chemical-shift values indicate the size of the ring in which boron is involved. Use of this method and p.m.r. spectroscopy showed that D-glucose forms a 1,2-furanoid and 1,2-pyranoid complex in the presence of borax and benzeneboronic acid. |
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