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Enzymatic synthesis of alkyl xylobioside and xyloside from xylan and alcohol
Authors:Shuichi Matsumura  Yasuyoshi Kinta  Kazuya Sakiyama  Kazunobu Toshima
Institution:(1) Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1, Hiyoshi, Kohoku-ku, 223 Yokohama-shi, Japan
Abstract:Summary Alkyl beta-D-xylobioside and alkyl beta-D-xyloside were prepared by the one-pot reaction of xylan and a fatty alcohol, such as 1-octanol, 1-decanol, 2-octanol and 2-ethylhexanol using the cell-free culture filtrate of the xylan-assimilating strain, Aureobasidium pullulans KK415. Using this strain, a novel surfactant, alkyl beta-D-xylobioside, was produced as the main product when the alcohol and xylan was incubated at a temperature of 65 °C and pH 4.5.
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