Thermal conversion of alkaline lignin and its structured derivatives to porous carbonized materials |
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Authors: | Kijima Masashi Hirukawa Takaharu Hanawa Fuminori Hata Toshimitsu |
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Institution: | a Institute of Materials Science, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan b Research Institute for Sustainable Humanosphere, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan |
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Abstract: | Alkaline lignin was thermally converted to microporous carbon in ca. 50% yield by heating up from room temperature to 900 °C without activation process under flowing of an argon gas. The carbonized material prepared by heating up conditions of 1 °C min−1 showed 530 m2/g of the Brunauer-Emmett-Teller (BET) specific surface area, which increased to 740 m2/g after washing with water. Furthermore, alkaline lignin derivatives were structured as micron scale particles by micelle formation and polymer gelation techniques. Carbonization of the structured lignins could afford high porous materials having BET surface areas above 1000 m2/g without surface activation processes. |
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Keywords: | Lignin Pyrolysis Porous carbon Carbonization |
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