Steroidal saponins from the rhizomes of Paris delavayi |
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| Authors: | Ting Zhang Hai Liu Xue-Ting Liu Xiao-Qing Chen Qiang Wang |
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| Affiliation: | aMurad Research Center for Modernized Chinese Medicine, Shanghai University of Traditional Chinese Medicine, Shanghai 201203, China;bDepartment of Chinese Materia Medica Analysis, China Pharmaceutical University, Nanjing 210009, China;cShanghai Mass Spectrometry Center, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032, China;dDepartment of Chemistry, University of Wisconsin-La Crosse, La Crosse, WI 54601, USA |
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| Abstract: | Two new steroidal saponins, padelaosides A (1) and B (2), along with two other known steroidal saponins (3 and 4) were isolated from the rhizomes of Paris delavayi. Their structures were elucidated by 1D and 2D NMR techniques, HRFTMS, physical data and chemical methods. The two different absolute configurations of fucose, assigned as l and d that were found on compounds 1 and 2, respectively, were simultaneously reported in a natural medicine for the first time. |
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| Keywords: | Steroidal saponins Paris delavayi France Liliaceae smCaps" >d-Fucose smCaps" >l-Fucose |
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