High‐Performance Wide Bandgap Copolymers Using an EDOT Modified Benzodithiophene Donor Block with 10.11% Efficiency |
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Authors: | Kui Feng Guofang Yang Xiaopeng Xu Guangjun Zhang He Yan Omar Awartani Long Ye Harald Ade Ying Li Qiang Peng |
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Institution: | 1. Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry and State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, P. R. China;2. Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration & Reconstruction, Hong Kong University of Science and Technology, Kowloon, Hong Kong SAR;3. Department of Physics, North Carolina State University, Raleigh, NC, USA |
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Abstract: | Newly developed benzo1,2‐b:4,5‐b′]dithiophene (BDT) block with 3,4‐ethylenedioxythiophene (EDOT) side chains is first employed to build efficient photovoltaic copolymers. The resulting copolymers, PBDTEDOT‐BT and PBDTEDOTFBT, have a large bandgap more than 1.80 eV, which is attributed to the increased steric hindrance between the BDT and EDOT skeletons. Both copolymers possess the satisfied absorptions, low‐lying highest occupied molecular orbital (HOMO) levels and high crystallinity. Using the fluorination strategy, PBDTEDOT‐FBT exhibits a wider and stronger absorption and a deeper HOMO level than those of PBDTEDOT‐BT. PBDTEDOT‐FBT:6,6]‐Phenyl C71 butyric acid methyl ester (PC71BM) blend also shows the higher hole mobility and better surface morphology compared with the PBDTEDOTBT:PC71BM blend. Combination of above advantages, PBDTEDOT‐FBT devices exhibit much higher power conversion efficiency (PCE) of 10.11%, with an improved open circuit voltage (Voc) of 0.86 V, short circuit current densities (Jsc) of 16.01 mA cm?2, and fill factor (FF) of 72.6%. This work not only provides a newly efficient candidate of BDT donor block modified with EDOT conjugated side chains, but also achieves high‐performance large bandgap copolymers for polymer solar cells (PSCs) via the synergistic effect of fluorination and side chain engineering strategies. |
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Keywords: | ethylenedioxythiophene (EDOT) fluorination polymer solar cells side chain engineering wide bandgap copolymers |
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