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An Efficient and Earth‐Abundant Oxygen‐Evolving Electrocatalyst Based on Amorphous Metal Borides
Authors:Jean Marie Vianney Nsanzimana  Yuecheng Peng  Yang Yang Xu  Larissa Thia  Cheng Wang  Bao Yu Xia  Xin Wang
Institution:1. School of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore, Singapore;2. Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education, Hubei), Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, P. R. China;3. Institute for New Energy Materials and Low‐Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, P. R. China
Abstract:Cost‐effective and efficient oxygen‐evolving electrocatalysts are urgently required for energy storage and conversion technologies. In this work, an amorphous trimetallic boride nanocatalyst (Fe–Co–2.3Ni–B) prepared by a simple approach is reported as a highly efficient oxygen evolution reaction electrocatalyst. It exhibits an overpotential (η) of 274 mV to deliver a geometric current density (jgeo) of 10 mA cm?2, a small Tafel slope of 38 mV dec?1, and excellent long‐term durability at a mass loading of 0.3 mg cm?2. The impressive electrocatalytic performance originates from the unique amorphous multimetal–metalloid complex nanostructure. From application's point of view, this work holds great promise as this process is simple and allows for large‐scale production of cheap, yet efficient, material.
Keywords:amorphous structures  electrocatalysts  electronic effects  metal boride  oxygen evolution
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