Remediation of Nitrobenzene Contaminated Soil by Combining Surfactant Enhanced Soil Washing and Effluent Oxidation with Persulfate

The combination of surfactant enhanced soil washing and degradation of nitrobenzene (NB) in effluent with persulfate was investigated to remediate NB contaminated soil. Aqueous solution of sodium dodecylbenzenesulfonate (SDBS, 24.0 mmol L^-1) was used at a given mass ratio of solution to soil (20:1) to extract NB contaminated soil (47.3 mg kg^-1), resulting in NB desorption removal efficient of 76.8%. The washing effluent was treated in Fe²⁺/persulfate and Fe²⁺/H₂O₂ systems successively. The degradation removal of NB was 97.9%, being much higher than that of SDBS (51.6%) with addition of 40.0 mmol L^-1 Fe²⁺ and 40.0 mmol L^-1 persulfate after 15 min reaction. The preferential degradation was related to the lone pair electron of generated SO₄•⁻, which preferably removes electrons from aromatic parts of NB over long alkyl chains of SDBS through hydrogen abstraction reactions. No preferential degradation was observed in •OH based oxidation because of its hydrogen abstraction or addition mechanism. The sustained SDBS could be reused for washing the contaminated soil. The combination of the effective surfactant-enhanced washing and the preferential degradation of NB with Fe²⁺/persulfate provide a useful option to remediate NB contaminated soil.