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Glycosylation of acid sensitive acceptors. Synthesis of (2,3-epoxy-1-propyl) glycosides |
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| Authors: | Kasprzycka Anna Szeja Wiesław Grynkiewicz Grzegorz |
| Affiliation: | Silesian Technical University, Department of Chemistry, Krzywoustego 4, 44-100 Gliwice, Poland. akasprzycka@interia.pl |
| Abstract: | Treatment of O-benzylated derivatives of glycosyl N-allyl thiocarbamate with racemic or enantiomerically pure glycidol and bromine provides the 1,2-cis-glycidyl glycosides. This protocol was mild, highly stereoselective and efficient. |
| Keywords: | Glycidyl glycosides Glycosides Glycosylation N-Allyl thiocarbamates |
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