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Geometric isomers of sex pheromone components do not affect attractancy of Conopomorpha cramerella in cocoa plantations
Authors:W Vanhove  N Vanhoudt  K R M Bhanu  S Abubeker  Y Feng  M Yu  P Van Damme  A Zhang
Institution:1. Laboratory of Tropical and Subtropical Agriculture and Ethnobotany, Department of Plant Production, Ghent University, Gent, Belgium;2. Barry Callebaut Malaysia Sdn. Bhd., Padang Tengku, Kuala Lipis, Malaysia;3. Pest Control (India) Pvt. Ltd‐BCRL, Bangalore, India;4. US Department of Agriculture, Agricultural Research Service, Invasive Insect Biocontrol and Behavior Laboratory, Beltsville, MA, USA;5. College of Food Science and Nutritional Engineering, China Agriculture University, Beijing, China;6. Faculty of Tropical AgriSciences, Czech University of Life Sciences Prague, Prague, Czech Republic
Abstract:The cocoa pod borer (CPB), Conopomorpha cramerella (Snellen), sex pheromone was previously identified as a blend of (E,Z,Z)‐ and (E,E,Z)‐4,6,10‐hexadecatrienyl acetates and corresponding alcohols. These pheromone components were synthesized by modification of an existing method and the relative attractiveness of synthetic blends that included different levels of non‐target pheromone components and chemical purities was tested in a cocoa field using Delta traps. Male captures were not significantly different among traps baited with pheromone blends containing 5% to 47% (based on four identified pheromone components) of other geometric acetates (E,Z,E)‐, (Z,Z,Z)‐, (Z,E,Z)‐ and (Z,E,E)‐4,6,10‐hexadecatrienyl acetates], indicating that C. cramerella males did not discriminate among the pheromone components and other geometric isomers in the blends. Therefore, neither antagonistic nor synergistic effects from other pheromone geometric isomers were observed. The modified synthetic pathway offers the prospect of more economical production of CPB sex pheromone. During 17 weeks when C. cramerella monitoring coincided with the main cocoa pod harvest period in 2013–2014, CPB trap catch data from some blends showed a good correlation with the number of pods with C. cramerella infestation symptoms.
Keywords:(E  E  Z)‐4  6  10‐hexadecatrienyl acetate  (E  Z  Z)‐4  6  10‐hexadecatrienyl acetate  chemical synthesis  cocoa pod borer  integrated pest management     Theobroma cacao   
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