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Single-crystal EPR studies of a spin-frustrated imidazolate-bridged trinuclear copper(II) complex |
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| Authors: | Juan Padilla Dante Gatteschi Phalguni Chaudhuri |
| Affiliation: | a Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, PO Box 55-534, México, D.F. 09820, México b Department of Chemistry, University of Florence, Via Maragliano 77, 50144, Florence, Italy c Max-Planck-Institut für Strahlenchemie, Stiftstrasse 34–36, D-45470, Mülheim on der Ruhr, Germany |
| Abstract: | The single-crystal and polycrystalline powder EPR spectra of the trinuclear compound [L3Cu3(Im)3](ClO4)3, L = 1,4,7-trimethyl-1,4,7-triazacyclononane, and Im = imidazolate, have been measured in the temperature range 4.2–300 K. The spectra are explained based on the spin-frustration, the low symmetry, and the intercluster exchange interactions. |
| Keywords: | EPR Spin-frustration Imidazolate Trimer Copper(II) |
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