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A novel ferromagnetic coupling one-dimensional complex {Cu(II)(NIT3Py)2[N(CN)2]2(H2O)2} |
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| Authors: | Chen-Xi Zhang Dai-Zheng Liao Shi-Ping Yan |
| Affiliation: | a Department of Chemistry, NanKai University, Tianjin 300071, People’s Republic of China b State Key Laboratory of Coordination Chemistry, Nanjing 210093, People’s Republic of China |
| Abstract: | The novel ferromagnetic coupling one-dimensional complex {Cu(NIT3Py)2[N(CN)2]2(H2O)2} (NIT3Py=2-(3′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized structurally and magnetically. It crystallizes in the monoclinic space group C2/c. The Cu(II) ion is in a distorted octahedral environment. The units of {Cu(NIT3Py)2[N(CN)2]2(H2O)2} were connected as one-dimensional structure by the intermolecular hydrogen bonds. Magnetic measurements show that there are intramolecular ferromagnetic interactions and intermolecular antiferromagnetic interactions within the chain. |
| Keywords: | Crystal structures Nitronyl nitroxide radicals Copper(II) complexes Ferromagnetic interactions |
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