Theory of isomerization equilibrium in electrophoresis. I |
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| Authors: | CANN J R KIRKWOOD J G BROWN R A |
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| Affiliation: | 2. From the Sterling Chemistry Laboratory, Yale University, New Haven, Connecticut USA;3. From the Lederle Laboratories, Pearl River, New York USA;1. Autoimmune Endocrine Diseases Unit, Bambino Gesù Children''s Hospital, Research Institute, Rome, Italy;2. Endocrinology and Diabetology Unit, Bambino Gesù Children''s Hospital, Research Institute, Rome, Italy;3. Division of Auxology, Italian Auxological Institute, Research Institute, Piancavallo, Verbania, Italy;4. Pediatric Department, S. Raffaele Hospital, Milan, Italy;5. Pediatric Endocrinology, Regina Margherita Hospital, Turin, Italy;6. Department of Pediatric Science and Surgery, Pediatric Hospital Giovanni XXIII, Bari, Italy;7. Pediatric Unit, Insubria University, Varese, Italy;8. Pediatric Unit, Oasi Maria SS, Research Institute, Troina, Enna, Italy;9. Pediatric Department, University of Padua, Italy;10. Department of Translational Sciences, University Federico II, Naples, Italy;11. Pediatric Endocrinology and Rare Diseases Unit, University of Bologna, Italy;12. Pediatric Unit, Salvini Hospital, Rho, Milan, Italy;1. Institute of Socio-Arts and Sciences, The University of Tokushima, 1-1 Minamijosanjima-cho, Tokushima 770-8502, Japan;2. Research Institute for Sustainable Humanosphere, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan;3. Institute of Sustainability Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan;4. Nara Forest Research Institute, 1 Kibi, Takatori-cho, Takaichi-gun, Nara 635-0133, Japan;1. IRCCS SDN, Via Emanuele Gianturco 113, 80143 Napoli, Italy;2. Dipartimento di Scienze e Tecnologie, Università di Napoli Parthenope, Isola C4, Centro Direzionale, 80143 Napoli, Italy;3. Dipartimento di Medicina Molecolare e Biotecnologie Mediche, Università degli Studi di Napoli Federico II, Via Sergio Pansini 5, 80131 Napoli, Italy;4. CEINGE Biotecnologie Avanzate S.C. a r.l., Via Gaetano Salvatore 486, 80145 Napoli, Italy;5. Dipartimento di Medicina Clinica e Chirurgia, Università degli Studi di Napoli Federico II, Via Sergio Pansini 5, 80131 Napoli, Italy;1. Department of Gynecology, The fourth Affiliated Hospital of China Medical University, 4 Chongshandong road, Huanggu district, Shenyang, Liaoning 110004, PR China;2. Department of Immunology, College of Basic Medical Science, China Medical University, Shenyang 110122, China;3. Cytocm lnc, 3001 Aloma Ave. Winter Park, FL 32792, USA;4. Department of Oncology, Shengjing Hospital of China Medical University, Shenyang 110004, China;1. Instituto de Tecnologia Química e Biológica António Xavier (ITQB-NOVA), Universidade Nova de Lisboa, Av. da República (EAN), 2780-157 Oeiras, Portugal;2. Magnetic Resonance Center and Department of Chemistry, University of Florence, Via L. Sacconi 6, 50019 Sesto Fiorentino, Italy |
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| Abstract: | ![]()
The general theory of electrophoresis and sedimentation of two-component equilibrium systems, A ⇋ B, is described. An approximate analytical solution and illustrative calculation for the special case where the rates of reaction in the two directions are equal, are presented. These calculations indicate that resolution of the schlieren patterns into two peaks should occur for times of electrophoresis less than the halftime of the reactions. |
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