Structure and spectroscopic studies of cis-bis(bipyridine) ruthenium(II) complexes of phenylcyanamide ligands |
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| Authors: | Anthony Baker |
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| Institution: | NanoScience Group, CEMES-GNS/CNRS, 29 rue Jeanne Marvig, BP 94347, 31055 Toulouse Cedex 4, France |
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| Abstract: | New ruthenium(II) complexes with cyanamide ligands, cis-Ru(bpy)2(Ipcyd)2] (1) and Ru(bpy)2(OHpcyd)2] (2) (bpy = 2,2′-bipyridine, Ipcyd = 4-iodophenylcyanamide anion, OHpcyd = 4-(3-hydroxy-3-methylbut-1-ynil)phenylcyanamide), have been prepared and characterized by UV-Vis, IR and 1H NMR spectroscopies as well as electrochemical technique (CV). The complex cis-Ru(bpy)2(Ipcyd)2] (1) crystallized with empirical formula of C34H24I2N8Ru in a monoclinic crystal system and space group of P21/c with a = 11.769(7) Å, b = 24.188(12) Å, c = 11.623(2) Å, β = 91.63(3)°, V = 3308(3) Å3 and Z = 4. |
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| Keywords: | Ruthenium compounds Phenylcyanamide ligand Bipyridine Crystal structures |
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