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Synthesis and crystal structures of trans-dichlorobis{tri(2-methylphenyl)stibine}palladium(II) and trans-dibromobis{tri(2-methylphenyl)stibine}palladium(II) |
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| Authors: | Ayfer Mentes John Fawcett |
| Affiliation: | a Department of Chemistry, Arts and Science Faculty, Zonguldak Karaelmas University, 67100 Zonguldak, Turkey b X-ray Crystallography Laboratory, Department of Chemistry, The University of Leicester, Leicester, LE1 7RH, UK |
| Abstract: | Tri(2-methylphenyl)stibine reacts with [PdX2(cod)] or PdX2 (X = Cl or Br) to give the trans-[PdX2{Sb(2-Me- C6H4)3}2]. The single crystal X-ray structures of trans-[PdX2{Sb(2-Me-C6H4)3}2] (X = Cl or Br) revealed that the palladium atom is a square planar environment with mutually trans-Sb(2-methylphenyl)3 ligands. Iodine analogous of complex can also be prepared from trans metallation reaction with sodium iodine. |
| Keywords: | Antimony Crystal structures Tri(2-methylphenyl)stibine Palladium(II) Trans metallation |
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