Novel oxorhenium(V) ‘3+1’ mixed ligand complexes with 3-thiapentane-1,5-dithiolate and functional mercaptobenzoyl amino acid ethyl ester |
| |
| Authors: | Shubhamoy Chowdhury |
| |
| Affiliation: | Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, 2-12-1-N1-34 O-okayama, Meguro-ku, Tokyo 152-8550, Japan |
| |
| Abstract: | Oxorhenium(V) complexes with ‘3+1’ mixed ligands, [ReO(SSS)L], where SSS is η3-(SCH2CH2SCH2CH2S), L = η1-(C6H4COOH-4-S), η1-(C6H4CONHCH2COOEt-4-S), η1-(C6H4CONHCH(CH3)COOEt-4-S), and η1-(C6H4CONHCH(CH2Ph)COOEt-4-S), have been synthesized. These L ligands and [ReO(SSS)L] complexes were characterized by IR, 1H NMR, 13C NMR, and MAS spectrometers. Molecular structure of [ReO(SSS){η1-(C6H4COOH-4-S)}] complex was determined to be a distorted square pyramidal by single crystal X-ray analytical method. |
| |
| Keywords: | Oxorhenium(V) complexes Molecular structure Amino acid esters &lsquo 3+1&rsquo mixed ligands Thiolate |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
