Dimeric thiophosphorus complexes of sodium and zinc: Structural characterization of [(THF)2NaO(S)PPh2]2 and [Zn{S2P(OMe)C6H4OEt-p}2]2 |
| |
| Authors: | Steffen Blaurock Ionel Haiduc |
| |
| Institution: | a Chemisches Institut, Otto-von-Guericke-Universität Magdeburg, D-39106 Magdeburg, Germany
b Facultatea de Chimie, Universitatea “Babes-Bolyai”, RO-3400 Cluj-Napoca, Romania |
| |
| Abstract: | Sodium P,P-diphenylphosphinothioate (2) was prepared by treatment of the free acid, Ph2P(S)OH (1), with sodium bis(trimethylsilyl)amide and isolated as its THF adduct. The zinc phosphonodithioate complex Zn{S2P(OMe)C6H4OEt-p}2]2 (3) was obtained from ZnCl2 and the readily accessible sodium salt of the ligand. According to X-ray diffraction studies, both compounds form dimers in the solid state. |
| |
| Keywords: | Phosphinothioate ligands Phosphonodithioate ligands Sodium Zinc Crystal structures |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
