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Structure of acidic o-specific polysaccharide from the marine bacterium <Emphasis Type="Italic">Cellulophaga baltica</Emphasis>
Authors:S V Tomshich  N A Komandrova  G Widmalm  O I Nedashkovskaya  A S Shashkov  A V Perepelov
Institution:(1) Pacific Institute of Bioorganic Chemistry, Far East Division, Russian Academy of Sciences, prosp. Stoletiya Vladivostoka 159, Vladivostok, 690041, Russia;(2) Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91 Stockholm, Sweden;(3) Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia
Abstract:
The structure of an acidic O-specific polysaccharide from the marine bacterium Cellulophaga baltica was established by chemical methods and NMR spectroscopy. The polysaccharide was shown to consist of repeating tetrasaccharide units containing two mannose residues, one N-acetyl-D-glucosamine residue, and one D-glucuronic acid residue. An O-acetyl group was also found in the polysaccharide in nonstoichiometric amount. The polysaccharide had the following structure:
Keywords:Cellulophaga baltica  marine bacteria  O-specific polysaccharide  structure  NMR spectroscopy
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