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The Impact of Indigenous Microorganisms on the Mineral Corrosion and Mineral Trapping in the SO2 Co-injected CO2-Saline-Sandstone Interaction
Authors:Fengjun Zhang  Yunpeng Song  Chenyang Li  Shengyu Zhang  Kai Fan
Institution:1. Key Lab of Groundwater Resources and Environment Ministry of Education, Jilin University, Changchun, P. R. China;2. Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun, P. R. China;3. Key Laboratory of Songliao Aquatic Environment Ministry of Education, Jilin Jianzhu University, Changchun, P. R. China;4. Yulin Environmental Protection Bureau, Yulin, P. R. China
Abstract:The impact of indigenous microorganisms on the mineral corrosion and mineral trapping in the SO2 co-injected CO2-saline-sandstone interaction was investigated in this study by lab experiments under 55?°C, 15?M pa. The results verified that co-injection of SO2 resulted in a decrease in biomass and shifts in microbial communities within 90?days, but some microorganisms still could adapt to acidic, high-temperature, high-pressure, and high-salinity environments. Firmicutes and Proteobacteria remained dominant phylum, but phylum Proteobacteria showed better tolerance to the co-injection of SO2 in the initial period. In the SO2 co-injected CO2-saline-sandstone interaction under microbial mediation, acid-producing bacteria further promoted the corrosion of K-feldspar, albite, and clay minerals, meanwhile mobilizing more K+, Na+, Ca2+, Mg2+ into solution. The acidogenic effect may be linked to the dominant genus of Bacillus, Paenibacillus, Acinetobacter, Pseudomonas and Exiguobacterium. Co-injection of SO2 inhibited the carbonates capture, while microbial acid production further reduced the pH, further inhibiting carbonates capture. As a result, no secondary carbonate (e.g., calcite) was observed on a short time scale within 90?days. So, microbial acidogenic effect was not conducive to carbonates capture in short term.
Keywords:CO2 sequestration  SO2  indigenous microorganisms  acid-producing bacteria  anhydrite
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