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Species-strain dependence of stereoselectivity in microbial oxidation of thioethers
Authors:Barbara J. Auret  Derek R.Boyd  H.Bernard Henbest  Christopher G. Watson  Krešimir Balenović  V. Polak  Vera Johanides  S. Divjak
Affiliation:Department of Chemistry, Queen''s University, Belfast BT9 5AG Ireland;Institute of Organic Chemistry and Biochemistry, Zagreb 4100 Yugoslavia;Laboratory of Industrial Microbiology, Faculty of Technology, University of Zagreb, Zagreb 4100, Yugoslavia
Abstract:The stereoselectivity in the aerobic, microbial oxidation of thioethers and sulphoxides is shown to be dependent on species and strain. A strain of Aspergillus niger was used to obtain an optically active dialkyl sulphoxide.
Keywords:Phycomycetes  fungi  fungal oxygen atom transfer at sulphur  stereoselectivity  strain-species dependence.
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