A new chemical synthesis of 5alpha-cholest-8(14)-en-3beta,5alpha-diol |
| |
| Authors: | Parish E J Luo C Boos T L |
| |
| Affiliation: | Department of Chemistry, Auburn University, Auburn, AL 36849-5312, USA. |
| |
| Abstract: | Reduction of 3beta-benzoyloxy-14alpha,15alpha-epoxy-5alpha-cholest-7-ene with lithium in ethylenediamine gave 5alpha-cholest-8(14)-en-3beta, 5alpha-diol in high yield. This procedure offers an alternate synthesis through the reductive rearrangement of an alpha,beta-unsaturated steroidal epoxide. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
