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N-Acyl derivatives of Asn,new bacterial N-acyl D-amino acids with surfactant activity
Authors:F. Peypoux  O. Laprévote  M. Pagadoy  J. Wallach
Affiliation:(1) Laboratoire de Biochimie Analytique et Synthèse Bioorganique, Université Claude Bernard, Villeurbanne, France;(2) Institut de Chimie des Substances Naturelles, CNRS, Gif-sur-Yvette, France
Abstract:
Summary. New N-acyl D-amino acids were isolated from Bacillus pumilus IM 1801. Their structures were determined by chemical analysis and mass spectrometry. The lipid part was identified as a mixture of fatty acids with 11, 12, 13, 15, and 16 carbon atoms in the iso, anteiso or n configuration linked by an amide bond with a D-asparagine. They exhibited surfactant properties.
Keywords:: N-acyl D-amino acids –   Mass spectrometry –   Bacillus pumilus –   Surfactant activity
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