Field-dependent proton relaxation in aqueous solutions of some manganese(II) complexes: a new interpretation |
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| Authors: | Danuta?Kruk Jozef?KowalewskiEmail author |
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| Affiliation: | Division of Physical Chemistry, Arrhenius Laboratory, Stockholm University, 106 91, Stockholm, Sweden. |
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| Abstract: | Field-dependent measurements of the paramagnetic relaxation enhancement for water protons in the presence of Mn(II) complexes ( S=5/2), reported recently, are re-interpreted using theoretical models that take into consideration the fact that the relaxation of the electron spin for S>1 is multiexponential (even in the Redfield limit) and that are valid for an arbitrary relation between the electronic Zeeman interaction and the zero-field splitting in the complex. |
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