Asymmetric Total Synthesis of ent-Sandaracopimaradiene,a Biosynthetic Intermediate of Oryzalexins |
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Abstract: | ![]() An asymmetric total synthesis of ent-sandaracopimaradiene, a biosynthetic intermediate of oryzalexins, via B-alkyl Suzuki-Miyaura coupling and Lewis acid-mediated B-ring formation as key steps was achieved. |
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Keywords: | phytoalexin rice blast disease sandaracopimaradiene biosynthesis |
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