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Asymmetric Total Synthesis of ent-Sandaracopimaradiene,a Biosynthetic Intermediate of Oryzalexins
Abstract:
An asymmetric total synthesis of ent-sandaracopimaradiene, a biosynthetic intermediate of oryzalexins, via B-alkyl Suzuki-Miyaura coupling and Lewis acid-mediated B-ring formation as key steps was achieved.
Keywords:phytoalexin  rice blast disease  sandaracopimaradiene  biosynthesis
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