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Neolignans from a Nectandra species
Authors:Raimundo Braz Filho  Roberto Figliuolo  Otto R Gottlieb
Institution:Instituto de Ciências Exatas, Universidade Federal Rural do Rio de Janiero, Municipio de Itaguaí RJ , Brazil
Abstract:The trunk wood of an Amazonian Nectandra (Lauraceae) species contains one bicyclo3.2.1]octanoid and four hydrobenzofuranoid neolignans. The latter comprise representatives of the mirandin, the rearranged burchellin and the burchellin types. The former was characterized as (1S, 4R, 5S, 6R, 7R)-3-allyl-4-hydroxy-1-methoxy-(3′, 4′, 5′-trimethoxyphenyl)- 7-methyl-8-oxobicyclo3.2.1]oct-2-ene macrophyllin-B), a new representative of the seemingly rare macrophyllin type.
Keywords:Lauraceae  hydrobenzofuranoid neolignans  bicyclo[3  2  1]octanoid neolignans    Ve=3  4-dimethoxyphenyl (veratryl)  Pi=3  4-methylenedioxyphenyl (piperonyl)  
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