排序方式: 共有29条查询结果,搜索用时 15 毫秒
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Qian Cheng Zhiyuan Chen Qing Zhang Senqiang Zhu Rui Liu Hongjun Zhu 《Luminescence》2022,37(2):247-254
Three A–π–A or D–π–D perylene diimide ( PDI ) derivatives with varied groups on π-conjugate were synthesized and characterized. The photophysical properties of these compounds were systematically studied by spectral experiments and density functional theory calculations. All compounds displayed intense absorption bands at 300–800 nm wavelengths. However, diverse groups on the π-conjugate influenced the UV–vis absorption. Electron-withdrawing groups on PDI-2 caused a slight red shift at the 350–400 nm wavelength and a blue shift after 400 nm wavelength. At the same time, the electron-donating substituents on PDI-3 caused an obvious red shift of this band. These PDI derivatives exhibited emission in solution at room temperature (λem = 500–850 nm). The quantum yield of PDI-3 decreased, while the electron-donating substituents were introduced to the π-conjugated motifs. However, the quantum yield of PDI-2 increased when electron-withdrawing substituents were introduced to the π-conjugated motifs. In addition, PDI-1 and PDI-2 exhibited broad triplet transient absorption in the visible region. These photophysical properties could help us to understand the relationship between structure and photophysical properties of perylene diimide derivatives and exploit more original perylene diimide-based optical functional materials. 相似文献
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Electrochemical detection of nucleic base mismatches was attempted successfully with ferrocenyl naphthalene diimide (FND) in a model system with 20-meric double-stranded oligonucleotides with or without a mismatch(es). Thus, dA(20) or a 20-meric sequence of the lac Z gene was immobilized on a gold electrode and complementary oligonucleotides with different numbers of mismatches were allowed to hybridize in the presence of FND to give rise to an electrochemical signal. The signal intensity varied depending on the number of unpaired bases on the DNA duplex. From experiments with a quartz crystal microbalance, eight molecules of FND were found to bind to the 20-meric double-stranded oligos and this number decreased as the number of mismatches increased. These findings were further supported by matrix-assisted laser desorption ionization time-of-flight mass spectroscopy. This novel method will be useful for the analysis of single-nucleotide polymorphisms present on human genes. 相似文献
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Xing-Qiang Lü Li Zhang Chun-Long Chen Cheng-Yong Su Bei-Sheng Kang 《Inorganica chimica acta》2005,358(6):1771-1776
Two 1D organic-inorganic coordination polymers, [Cd(3-pmpmd)(CH3CN)2(H2O)2]n · 2n(ClO4)2 (1) and [Zn(3-pmpmd)1.5(H2O)2]n · 2n(ClO4)2 · nCH3CN (2), were obtained from M(ClO4)2 (M = Cd, Zn) and the semi-flexible 3,3′-N-donor bis-pyridyl ligand 3-pmpmd: 1 has an 1D zigzag framework with 3-pmpmd in the ZT-mode (anti, trans-) conformation, while 2 has an 1D rod and loop network with 3-pmpmd in both ZT- and ZC-mode (anti, cis-) conformations. Results showed that the metal ions could influence the coordination mode of a semi-flexible bis-pyridyl ligand. 相似文献
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Effect of Ring‐Fusion on Miscibility and Domain Purity: Key Factors Determining the Performance of PDI‐Based Nonfullerene Organic Solar Cells 下载免费PDF全文
Huawei Hu Yunke Li Jianquan Zhang Zhengxing Peng Lik‐kuen Ma Jingming Xin Jiachen Huang Tingxuan Ma Kui Jiang Guangye Zhang Wei Ma Harald Ade He Yan 《Liver Transplantation》2018,8(26)
Compared to the rapid development of nonfullerene organic solar cells (OSCs) based on the state‐of‐the‐art indacenodithiophene (IDT)‐based small molecule acceptors (SMAs), the progress for perylene diimide (PDI)‐based electron acceptors has lagged behind owing to the lack of understanding on the structure–morphology–performance relationship of PDI SMAs. Given the ease of synthesis for PDIs and their high intrinsic electron mobility, it is crucial to identify key material parameters that influence the polymer:PDI blend morphology and to develop rational approaches for molecular design toward high‐performance PDI‐based SMAs. In this study, three pairs of PDI‐based SMAs with and without ring‐fusion are investigated and it is found that ring‐fusion and domain purity are the key structural and morphological factors determining the fill factors (FFs) and efficiencies of PDI‐based nonfullerene OSCs. This data shows that nonfullerene OSCs based on the ring‐fused PDI‐based SMAs exhibit much higher average domain purity and thus increased charge mobilities, which lead to enhanced FFs compared to those solar cells based on nonfused PDIs. This is explained by higher Florry Huggins interaction parameters as observed by melting point depression measurements. This study suggests that increasing repulsive molecular interactions to lower the miscibility between the polymer donor and PDI acceptor is the key to improve the FF and performance of PDI‐based devices. 相似文献
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Reactions between sulfur diimides R(NSN)R′ (R=R′=tBu (1a), SiMe3 (1b), SnMe3 (1c); R=tBu, R′=SnMe3 (1d); R=SiMez3, R′=SnMe3 (1e)) and various organoboranes were studied, and the products were characterized by multinuclear magnetic resonance data (1H, 11B, 13C, 15N, 29Si and 119Sn NMR). Tetraalkyldiboranes(6) (Et2BH2BEt2 (2), dimeric 9-borobicyclo[3,3.1]nonane (3)) react with 1a and 1b by 1,3-hydroboration to give the N-sulfanyl-dialkylaminoboranes 4 and 5 which are instable with respect to eliminatio of short-lived [R---NS]. Trialkylboranes (Et3B (8)) react only sluggishly with 1a, but more readily with 1b mainly via S-ethylation, formally a 1,2-ethyloboration, to give the diethylborylamido-imino-ethanesulfinic acid 9b decomposes slowly at room temperature via ethene elimination to give 4b, followed by further decomposition via [R---NS] elimination. The compounds 9 can be prepared independently from the reaction between the N-lithio-imino-ethanesulfinic acid amide 10 and diorganoboron halides. The molecular structure of the lithium amide 10a (R=R′=tBu) was determined by X-ray analysis as a dimer in which the four nitrogen, two sulfur and two lithium atoms adopt a boat conformation, in contrast with other known derivatives of this type. If the sulfur diimides bear at least one trimethylstannyl group (1c-e), their reactions with Et3B (8), iPr3B (12) or 9-iso-butyl-9-borabicyclo[3,3,1]nonane (13) lead to the novel aminoboranes 14–16. These are products of a 1,1,-organoboration, since the Me3Sn group moves from one nitrogen atom to the other, and both the boryl and an alkyl group end up at the same nitrogen atom. 相似文献
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NDI‐Based Small Molecule as Promising Nonfullerene Acceptor for Solution‐Processed Organic Photovoltaics 下载免费PDF全文
Yao Liu Lei Zhang Hyunbok Lee Hsin‐Wei Wang Annikki Santala Feng Liu Ying Diao Alejandro L. Briseno Thomas P. Russell 《Liver Transplantation》2015,5(12)
A novel naphthalene diimide (NDI)‐based small molecule (BiNDI) is designed and synthesized by linking two NDI monomers via a vinyl donor moiety. The electronic structure of BiNDI is carefully investigated by ultraviolet photoelectron spectroscopy (UPS). Density functional theory (DFT) sheds further light on the molecular configuration and energy level distribution. Thin film transistors (TFT) based on BiNDI show a highest electron mobility of 0.365 cm2 V?1 s?1 in ambient atmosphere. Organic photovoltaics (OPVs) by using BiNDI as the acceptor show a highest power conversion efficency (PCE) of 2.41%, which is the best result for NDI‐based small molecular acceptors. Transmission electron microscopy (TEM), atomic force microscopy (AFM), grazing incidence wide‐angle X‐ray diffraction (GIXD), and X‐ray photoelectron spectroscopy (XPS) characterization to understand the morphology and structure order of the bulk heterojunction film are performed. It is found that small amount of 1,8‐diiodooctane (DIO) (i.e., 0.5%) in the blended film facilitates the crystallization of BiNDI into fibrillar crystals, which is beneficial for the improvement of device performance. 相似文献
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Rossetti L D'Isa G Mauriello C Varra M De Santis P Mayol L Savino M 《Biophysical chemistry》2007,129(1):70-81
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Md. Monirul Islam Shinobu Sato Shingo Shinozaki Shigeori Takenaka 《Bioorganic & medicinal chemistry letters》2017,27(2):329-335
To identify an effective ligand that binds to a G-quadruplex structure but not a double-stranded DNA (dsDNA), a set of biophysical and biochemical experiments were carried out using newly synthesized cyclic ferrocenylnaphthalene diimide (cFNDI, 1) or the non-cyclic derivative (2) with various structures of G-quadruplex DNAs and dsDNA. Compound 1 bound strongly to G-quadruplexes DNAs (106 M?1 order) with diminished binding to dsDNA (104 M?1 order) in 100 mM AcOH-AcOK buffer (pH 5.5) containing 100 mM KCl. Interestingly, 1 showed an approximately 50-fold higher selectivity to mixed hybrid-type telomeric G-quadruplex DNA (K = 3.4 × 106 M?1 and a 2:1 stoichiometry) than dsDNA (K = 7.5 × 104 M?1) did. Furthermore, 1 showed higher thermal stability to G-quadruplex DNAs than it did to dsDNA with a preference for c-kit and c-myc G-quadruplex DNAs over telomeric and thrombin binding aptamers. Additionally, 1 exhibited telomerase inhibitory activity with a half-maximal inhibitory concentration (IC50) of 0.4 μM. Compound 2 showed a preference for G-quadruplex; however, the binding affinity magnitude and preference were improved in 1 because the former had a cyclic structure. 相似文献
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A pair of new dibenz[cd,lm]perylene derivatives, juglanperylenone A (1a) and juglanperylenone B (1b), along with ten known compounds, including four anthraquinones (2–5), two coumarins (6–7) and four triterpenoids (8–11), were isolated from the stem bark of Juglans mandshurica Maxim. Their structures were elucidated on the basis of spectroscopic evidence, including 1D and 2D NMR, HR-TOF-MS, and by comparison with literature data. In addition, the chemotaxonomic significance of the isolates was also discussed in this paper. 相似文献