Neue,abgewandelte pseudoguajanolide aus Psilostrophe villosa

Investigation of the North American species Psilostrophe villosa afforded, in addition to known compounds, five new sesquiterpene lactones, which all turn out to be modified pseudoguaianolides, most of them closely related to hymenolide. However, one of the lactones is a new type of nor-pseudoguaianolide. Furthermore a new monoacetylated borneol-β-D-glucoside is present. The chemotaxonomic situation is discussed briefly.     

Three germacranolides and other constituents from Eremanthus species

The re-investigation of Eremanthus glomerulatus afforded three new germacranolides and a guaianolide, while from E. mollis two known furanoheliangolides and a new phenylpropanol derivative were isolated. The germacranolides most probably are precursors of the widespread glaucolides. The structures were elucidated by spectroscopic methods. The chemotaxonomic situation is discussed briefly.     

New germacranolides,guaianolides and rearranged Guaianolides from Lasiolaena santosii

The aerial parts of L. santosii afforded three new diterpenes, a phenylpropanol, three eudesmane derivatives, three germacranolides, seventeen guaianolides and four rearranged guaianolides of a, so far, unknown type. Furthermore, several known compounds were isolated. The structures of the new compounds, the separations of which caused difficulties, were elucidated by spectroscopic methods and by some chemical transformations. The chemotaxonomic situation is discussed briefly.     

Über die mikrobicide Wirkung von organischen Säuren und ihren Kupfersalzen

Ohne Zusammenfassung     

8-Hydroxypegolettiolide,a sesquiterpene lactone with a new carbon skeleton and further constituents from Pegolettia senegalensis

The investigation of Pegolettia senegalensis afforded several new sesquiterpene lactones, eight cis-6,12-germacra-trans,trans-1(10),4,11-trienolides, five cis-6,12-eudesmanolides, two elemanolides, 8,14-cyclogermacra-1(10),4,7(11)-trien-6,12-olide with a new carbon skeleton, three germacra-1(10),4,11(13)-trien-12-oic acids with ester residues at C-8, 18-hydroxygeranyl nerol, 1,3-dihydroxyoctadecane and a mixture of esters of 3,4-dihydroxy-dihydrocinnamyl alcohol. The structures were elucidated by high field ¹HNMR spectroscopy and some chemical transformations. The C-10 configuration of 6,12-cis-eudesmanolides from Calostephane divaricata and Inula crithmoides most likely has to be corrected. The chemotaxonomic situation of the genus Pegolettia and biogenetic considerations are discussed briefly.     

Die V?gel Borkum's

Ohne Zusammenfassung     

Merops apiaster in der Provinz Posen

Ohne Zusammenfassung