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1.
Biological treatment of landfill leachate usually results in low COD removals because of high chemical oxygen demand (COD), high ammonium-N content and presence of toxic compounds. Coagulation-flocculation with lime addition and air stripping of ammonia were used as pre-treatment in this study in order to improve biological treatability of the leachate. Pre-treated leachate was subjected to adsorbent supplemented biological treatment in an aeration tank operated in fed-batch mode. COD and NH(4)-N removal performances of powdered activated carbon (PAC) and powdered zeolite (PZ) were compared during biological treatment. Adsorbent concentrations varied between 0 and 5 gl(-1). Percent COD and ammonium-N removals increased with increasing adsorbent concentrations. Percent COD removals with PAC addition were significantly higher than those obtained with the zeolite. However, zeolite performed better than the PAC in ammonium-N removal from the leachate. Nearly 87% and 77% COD removals were achieved with PAC and zeolite concentrations of 2 gl(-1), respectively. Ammonium-N removals were 30% and 40% with PAC and zeolite concentrations of 5 gl(-1), respectively at the end of 30 h of fed-batch operation.  相似文献   

2.
Here we provide direct evidence through a series laboratory and field-scale experiments using different age refuse to treat landfill leachate that aged refuse exhibits increased leachate contaminants removal ability with refuse stabilization time addition. Ten-years aged refuse showed best contaminant removal in a laboratory-scale test, removing 70.0% (8340.0-2540.0 mg/L) chemical oxygen demand (COD) and 75.0% (910.0-215.0 mg/L) ammonium-N, as well as removing 61.5-67.0% COD and 50.4-58.1% ammonium-N with variable COD (9948.0-12286.0 mg/L) and NH3-N (780.0-1184.0 mg/L) in a field-scale test, respectively. When the 10-years aged refuse was disinfected by 20% NaClO (wt%), COD, biochemical oxygen demand (BOD5), total nitrogen (TN), and ammonium-N removal showed a dramatic decrease throughout operation time from 84.4-86.2% to 15.2-34.5%, 94.4-99.8% to 26.2-54.4%, 31.2-33.9% to 2.1-10.1%, and 88.5-90.1% to 1.5-14.5%, respectively, suggesting biodegradation is the dominant contaminant removal. Based on this finding, a 3-stages (8 years) age refuse bioreactor (ARB) was constructed to treat leachate and ARB efficiently reduced chemical oxygen demand (COD) from 5478.0-10842.0 mg/L to 261.0-1020 mg/L (87.8-96.2% removal), ammonium-N from 811.4-1582.0 mg/L to 8.5-43.3 mg/L (96.9-99.4%), respectively, in 18 months running. In summary, the present studies suggest that increased leachate contaminant biodegradation ability of aged refuse could be used directly to create an engineering approach to treat leachate with operational and economic advantages.  相似文献   

3.
The aim of this study was to assess the efficiency of leachate treatment by microbial oxidation in four connected on-site aerated lagoons at a landfill site. The landfill site was found to be in an ageing methanogenic state, producing leachate with relatively low COD (mean value 1740 mg l−1) and relatively high ammonium concentrations (mean value 1241 mg l−1). Removal of COD averaged 75%, with retention times varying from 11 to 254 days. Overall 80% of the N load was removed within the plant, some by volatilisation of ammonium. Microbial community profiling of the water from each lagoon showed a divergent community profile, presumably a reflection of the nutrient status in each lagoon. In municipal solid waste landfills under similar conditions, leachate treatment through a facultative aerobic system in which sequential aerobic and anaerobic microbial oxidations occurred can readily be achieved using a simple two-lagoon system, suggesting this technology can be economic to install and simple to run.  相似文献   

4.
In order to enhance the removal efficiency of chemical oxygen demand (COD) in the high-salinity landfill leachate, the dominant strains were isolated from high-salinity landfill leachate. The dominant strains and bacteria consortium were screened for COD treatment potential using an aerobic COD concentration decrease test. Ten strains, TJ01–TJ10, were isolated, of which six strains TJ02, TJ03, TJ05, TJ06, TJ07, and TJ09 were found to have higher COD removal when the single bacteria were added, all more than 20%. The most effective combination was TJ06 + TJ09; the COD removal efficiency reached 45.57%. 16S rDNA gene sequence analysis revealed that TJ06 and TJ09 belonged to the genus Bacillus. The effects of the dominant bacteria consortium on the high-salinity landfill leachate varied with pH value and the volume fraction of leachate. The COD removal efficiencies maintained higher when the pH value was 6–8 and the volume fractions of leachate were less than 80%. The result also suggested that there is little effect on the growth of TJ06 and TJ09 when the range of Cl concentration is 0–30,000 mg/L.  相似文献   

5.
A specific landfill leachate that contained 1.036 mgl−1of 2-chlorobiphenyl was used in the study (255 mg l−1 COD and 133 mg l−1 BOD5). Three, 2-l semi-continuous batch reactors (SBRs) were used to simulate the treatment potential of this method on a small scale. Aerobic digestion effectively reduced the leachates COD concentration. Regardless of dilution, the leachates COD reached a <20 mg l−1 equilibrium after 96 h exposure to aerobic digestion, however, increasing the level of dilution accelerated the process. In untreated leachate, the LC50 for Asellus aquaticus was 57% v/v leachate in deionised water and 5% for Gammarus pulex (96 h, static LC50 tests without nutrition and oxygen depleting conditions). After being exposed to aerobic digestion, these values rose to 95% and 40%, respectively. Prolonged exposure to a 1:20 sub-lethal dilution of the aforementioned leachate has been previously shown to affect the breeding colony size of Asellus aquaticus and a 1:66 dilution influenced the fecundity of a Gammarus pulex population. After remediation by aerobic digestion, however, the population dynamics of both test species remained unaltered.  相似文献   

6.
In order to reduce the leachate strength from landfill at source, a novel landfill, functional layer embedded landfill, was developed through the introduction of the functional layers, and a comparative study was conducted between the functional layer embedded landfill (FLEL, R1) and the conventional landfill (CL, R2). It was found that the pollutant in leachate effluent from R1 was 20-50%, 14-43% and 33-75% of that from R2, in terms of COD, TN and NH3-N. The cumulative movement of waste settlement was about 16.4 and 13.1 cm in R1 and R2 under the test period of 1 years, resulting in 13.7% and 10.9% of the original landfill height. Therefore, FLEL could save the land area and the cost of the leachate treatment process due to the reduction of leachate strength, and more waste could be disposed in landfill through the acceleration of the MSW degradation process, comparing to the CL.  相似文献   

7.
Three Microbial Fuel Cells (MFCs) were fluidically connected in series, with a single feed-line going into the 1st column through the 2nd column and finally as a single outflow coming from the 3rd column. Provision was also made for re-circulation in a loop (the outflow from the 3rd column becoming the feed-line into the 1st column) in order to extend the hydraulic retention time (HRT) on treatment of landfill leachate. The effect of increasing the electrode surface area was also studied whilst the columns were (fluidically) connected in series. An increase in the electrode surface area from 360 to 1080 cm2 increased the power output by 118% for C2, 151% for C3 and 264% for C1. COD and BOD5 removal efficiencies also increased by 137% for C1, 279% for C2 and 182% for C3 and 63% for C1, 161% for C2 and 159% for C3, respectively. The system when configured into a loop was able to remove 79% of COD and 82% of BOD5 after 4 days. These high levels of removal efficiency demonstrate the MFC system’s ability to treat leachate with the added benefit of generating energy.  相似文献   

8.

Background

Aerobic granular sludge has become an attractive alternative to the conventional activated sludge due to its high settling velocity, compact structure, and higher tolerance to toxic substances and adverse conditions. Aerobic granular sludge process has been studied intensively in the treatment of municipal and industrial wastewater. However, information on leachate treatment using aerobic granular sludge is very limited.

Methods

This study investigated the treatment performance of old landfill leachate with different levels of ammonium using two aerobic sequencing batch reactors (SBR): an activated sludge SBR (ASBR) and a granular sludge SBR (GSBR). Aerobic granules were successfully developed using old leachate with low ammonium concentration (136 mg L?1 NH4 +-N).

Results

The GSBR obtained a stable chemical oxygen demand (COD) removal of 70% after 15 days of operation; while the ASBR required a start-up of at least 30 days and obtained unstable COD removal varying from 38 to 70%. Ammonium concentration was gradually increased in both reactors. Increasing influent ammonium concentration to 225 mg L?1 N, the GSBR removed 73 ± 8% of COD; while COD removal of the ASBR was 59 ± 9%. The GSBR was also more efficient than the ASBR for nitrogen removal. The granular sludge could adapt to the increasing concentrations of ammonium, achieving 95 ± 7% removal efficiency at a maximum influent concentration of 465 mg L?1 N. Ammonium removal of 96 ± 5% was obtained by the ASBR when it was fed with a maximum of 217 mg L?1 NH4 +-N. However, the ASBR was partially inhibited by free-ammonia and nitrite accumulation rate increased up to 85%. Free-nitrous acid and the low biodegradability of organic carbon were likely the main factors affecting phosphorus removal.

Conclusion

The results from this research suggested that aerobic granular sludge have advantage over activated sludge in leachate treatment.
  相似文献   

9.
This study aims at evaluating the performance of a two-chambered continuously fed microbial fuel cell with new Ti–TiO2 electrodes for bioelectricity generation from young landfill leachate at varying strength of wastewater (1–50 COD g/L) and hydraulic retention time (HRT, 0.25–2 days). The COD removal efficiency in the MFC increased with time and reached 45 % at full-strength leachate (50 g/L COD) feeding. The current generation increased with increasing leachate strength and decreasing HRT up to organic loading rate of 100 g COD/L/day. The maximum current density throughout the study was 11 A/m2 at HRT of 0.5 day and organic loading rate of 67 g COD/L/day. Coulombic efficiency (CE) decreased from 57 % at feed COD concentration of 1 g/L to less than 1 % when feed COD concentration was 50 g/L. Increase in OLR resulted in increase in power output but decrease in CE.  相似文献   

10.
This study assessed the accumulation of Cd (II), Hg (II), Cr (VI) and Pb (II) in Gynerium sagittatum (Gs), Colocasia esculenta (Ce) and Heliconia psittacorum (He) planted in constructed wetlands treating synthetic landfill leachate. Sixteen bioreactors were operated in two experimental blocks. Metal concentrations in the influent and effluent; root, stem, branch and leaves of plants were analysed, as well as COD, N-NH4+, TKN, T, pH, ORP, DO, and EC. Average removal efficiencies of COD, TKN and NH4+-N were 66, 67 and 72%, respectively and heavy metal removal ranged from 92 to 98% in all units. Cr (VI) was not detected in any effluent sample. The bioconcentration factors (BCF) were 100 -102. The BCF of Cr (VI) was the lowest: 0.59 and 2.5 (L kg?1) for Gs and He respectively; whilst Cd (II) had the highest (130–135 L kg?1) for Gs. Roots showed a higher metal content than shoots. Translocation factors (TF) were lower, He was the plant exhibiting TFs >1 for Pb (II), Cr (T) and Hg (II) and 0.4–0.9 for Cd (II) and Cr (VI). The evaluated plants demonstrate their suitability for phytoremediation of landfill leachate and all of them can be categorized as metals accumulators.  相似文献   

11.
The constructed wetland (CW) was developed as a pilot integrated system for the capital city's old sanitary landfill site. It consisted of three interconnected beds, two of vertical flow and one of horizontal flow stage. The CW covered 311 m2 with an intermittent hydraulic load of 0.5 cm d−1, filled with sand media and planted with reeds and cattails. The performance efficiency of the CW systems was evaluated for 7 years through physical and chemical parameters. Some monitored parameters varied noticeable. The efficiency for COD was 50%, BOD5 (59%), ammonia nitrogen (51%), nitrate (negative), total phosphorus (P) (53%), sulfates (negative), sulfides (49%), chlorides (35%), and Fe (84%). The average concentrations of suspended solids, COD, BOD5, nitrate, total P, sulfates, sulfides, and Fe were below limits after treatment. The ratio between N and P showed a limited level of P for biological processes. The performance of the system did not vary significantly with regard to temperature, however, it varied with precipitation. The results showed that the CW system, as a tertiary system or as an independent system, could be a low-cost alternative for the treatment of leachate from old landfill sites.  相似文献   

12.
The behavior of dimethyl phthalate (DMP) from municipal solid waste (MSW) in the leachate and refuse of two simulated landfill bioreactors was compared. In one reactor, the leachate was circulated between a landfill and a methanogenic reactor, while the other reactor was operated using direct recirculation of the leachate. The results revealed that the original concentration of DMP in the refuse was approximately 3.3 μg g−1, and the concentration decreased greatly during decomposition of the waste in both reactors. The major loss of DMP from the landfill occurred in an active methanogenic environment in the later period, while the environment was acidic due to a high concentration of chemical oxygen demand (COD), volatile fatty acids (VFA), and contained a large volume of biologically degradable material (BDM) during the early stage. In addition, a high correlation was found between the residual DMP concentrations and the BDM of the refuse in both systems. Circulating the leachate between the landfill and a methanogenic reactor resulted in an increase in the biodegradability of MSW and the degree of waste stabilization. Furthermore, the removal of DMP was enhanced 14% in the landfill that was operated in conjunction with the methanogenic reactor when compared to the landfill in which there was direct leachate recirculation.  相似文献   

13.
Lou Z  Feng J  Zhong S  Yuan H  Zhu N 《Bioresource technology》2011,102(14):7057-7063
Two functional layers embedded landfills (FLELs), namely LR1 (with Layers 1 and 2) and LR2 (with double Layer 1), were conducted to evaluate their efficiency on the reduction of leachate strength at source and the acceleration of waste biodegradation process. It was found that the cumulative COD, NH3-N, leachate quantity and landfill settlement in LR1 was 63.0%, 34.6%, 94.8% and 80.4% of that in LR2 in the entire test periods, while the leachate effluents from these two reactors presented almost the same concentration at the end of the operation period. It could be concluded that leachate pollutants was removed immediately in Layer 2 through the physical-chemical reaction, while double Layer 1s contributed to the pollutant removal in a long run through the improvement of the micro-organism activities in landfill. The layer composition should be applied according to the landfill types, i.e. plain landfill using Layer 2 and valley landfill using Layer 1.  相似文献   

14.
Abstract

Treatment of landfill leachate is a challenge due to its complex chemical composition and high recalcitrance and because of high costs for conventional wastewater treatment. In our study, leachate from the Quitaúna Landfill, Sao Paulo Metropolitan Region, Brazil, was treated at a laboratory scale with a horizontal subsurface flow constructed treatment wetland (HF-CTW) operating under a recirculation regime. Two units planted with Heliconia psittacorum (HP) and Cyperus papyrus (CP), and one unplanted control unit were assessed. With a recirculation regime over 21?days, the planted units removed 40% of chemical oxygen demand (COD) while the control unit removed only 29%. True color removal efficiencies were 2, 22, and 23% for the control, HP, and CP HF-CTWs, respectively. The ammonium nitrogen removal efficiencies for a 21-day hydraulic retention time (HRT) were 63–81% for planted units and 72% for the control. The increase of the HRT from 7 to 21?days led to the enhancement of ammonium nitrogen removal but did not affect the COD and total nitrogen removals. This phenomenon is a consequence of leachate’s low biodegradability. The present study shows the importance of the HRT and plant presence for landfill leachate treatment using HF-CTWs.  相似文献   

15.
Leachate treatment is a challenging issue due to its high pollutant loads. There are several studies on feasible treatment methods of leachate. In the scope of this study, high organic content of young leachate was eliminated using an upflow anaerobic sludge blanket (UASB) and a membrane bioreactor (MBR) in sequence and effluent of the system was given to single reactor for high activity ammonia removal over nitrite (SHARON) and anaerobic ammonia oxidation (Anammox) reactors to remove nitrogen content. All reactors were set up at lab scale in order to evaluate the usage of these processes in sequencing order for leachate treatment. COD and TKN removal efficiencies were over 90 % in the combined processes which were operated during the study. The biodegradable portion of organic matter was removed with an efficiency of 99 %. BOD5 concentration decreased to 50 mg/L by UASB and MBR in sequence even the influent BOD5 concentration was over 8,000 mg/L. Although high nitrogen concentrations were observed in raw leachate, successful removal of nitrogen was accomplished by consecutive operations of SHARON and Anammox reactors. The results of this study demonstrated that with an efficient pretreatment of leachate, the combination of SHARON–Anammox processes is an effective method for the treatment of high nitrogen content in leachate.  相似文献   

16.
The effect of landfill age on municipal leachate composition   总被引:5,自引:0,他引:5  
The influence of municipal landfill age on temporal changes in municipal leachate quality on the basis of elaboration of 4 years monitoring of leachate from landfill in Wysieka near Bartoszyce (Poland) is presented in this study. In leachate, concentrations of organic compounds (COD, BOD(5)), nutrients (nitrogen, phosphorus), mineral compounds, heavy metals and BTEX were investigated. It was shown that the principal pollutants in leachate were organics and ammonia - as landfill age increased, organics concentration (COD) in leachate decreased from 1,800 mg COD/l in the second year of landfill exploitation to 610 mg COD/l in the sixth year of exploitation and increase of ammonia nitrogen concentration from 98 mg N(NH)/l to 364 mg N(NH4) /l was observed. Fluctuation of other indexes (phosphorus, chlorides, calcium, magnesium, sulfate, dissolved solids, heavy metals, BTEX) depended rather on season of the year (seasonal variations) than landfill age. Moreover, the obtained data indicate that despite of short landfill's lifetime some parameters e.g. high pH (on average 7.84), low COD concentration (<2,000 mg COD/l), low BOD(5)/COD ratio (<0.4) and low heavy metal concentration, indicated that the landfill was characterized by methanogenic conditions already at the beginning of the monitoring period.  相似文献   

17.
王树芹  赖娟  赵秀兰 《生态学报》2012,32(19):6128-6137
以草本花卉植物一串红和石竹为材料,通过盆栽试验研究了不同浓度垃圾渗滤液灌溉对土壤理化性质及生物学性质、植物生长、氮磷和重金属吸收的影响。渗滤液灌溉提高了土壤有机质、氮含量和电导率,其中,黄壤盐分积累速度大于紫色土,而对土壤磷和重金属含量的影响不明显,土壤脲酶活性随渗滤液浓度的提高呈先升高后降低趋势,紫色土和黄壤在渗滤液灌溉浓度分别为60%和40%时脲酶活性最强;随渗滤液浓度提高紫色土过氧化氢酶活性略为上升,黄壤过氧化氢酶活性降低。渗滤液灌溉使两种花卉根系生长受到抑制,但对植物地上部的生长发育存在低浓度促进高浓度抑制的双重作用。渗滤液灌溉可提高两种植物地上部的氮含量,对一串红磷含量影响不明显,使石竹磷含量降低,对Cu、Zn含量的影响因土壤和植物的不同而异,但高浓度渗滤液灌溉使两种植物Pb、Cr和Cd含量均提高。结果表明,适当浓度渗滤液灌溉具有改善土壤肥力,促进植物地上部生长发育的作用,渗滤液灌溉不会引起土壤和植物体内重金属过量积累,土壤氮过量积累导致的氮磷营养失调和盐分过度积累是高浓度渗滤液抑制植物生长的重要原因。从土壤性质变化和植物生长反应看,渗滤液灌溉浓度以20%—40%为佳。  相似文献   

18.
He R  Liu XW  Zhang ZJ  Shen DS 《Bioresource technology》2007,98(13):2526-2532
A sequential upflow anaerobic sludge blanket (UASB) and air-lift loop sludge blanket (ALSB) treatment was introduced into leachate recirculation to remove organic matter and ammonia from leachate in a lab-scale bioreactor landfill. The results showed that the sequential anaerobic-aerobic process might remove above 90% of COD and near to 100% of NH4+ -N from leachate under the optimum organic loading rate (OLR). The total COD removal efficiency was over 98% as the OLR increased to 6.8-7.7 g/l d, but the effluent COD concentration increased to 2.9-4.8 g/l in the UASB reactor, which inhibited the activity of nitrifying bacteria in the subsequent ALSB reactor. The NO3- -N concentration in recycled leachate reached 270 mg/l after treatment by the sequential anaerobic-aerobic process, but the landfill reactor could efficiently denitrify the nitrate. After 56 days operation, the leachate TN and NH4+ -N concentrations decreased to less than 200 mg/l in the bioreactor landfill system. The COD concentration was about 200 mg/l with less than 8 mg/l BOD in recycled leachate at the late stage. In addition, it was found that nitrate in recycled leachate had a negative effect on waste decomposition.  相似文献   

19.
Laboratory scale tests on phytodepuration of raw and pre-treated leachate from municipal sanitary waste were carried out with four vegetable aquatic and terrestrial species at different organic loads. We used the terrestrial species Stenotaphrum secundatum and the free-floating aquatic species Lemna minor, Eichhornia crassipes and Myriophyllum verticellatum to purify leachate from municipal solid waste. The organic load characterized by COD varied from 2–30 g m−2 day−1. Blanks using tap water served as controls. Duration of the experiments varied from 9–90 days. Maximum concentrations in the experiments were 1600 mg l−1 COD and 300 mg l−1 NH4–N for S. secundatum. Best results in terms of COD, BOD, and ammonia removal were obtained for raw leachate with COD=2 g m−2 day−1 in free water surface (FWS) wetlands, and with 2 and 5 g m−2 day−1 in subsurface flow (SSF) wetlands. Results show that for pretreated leachate (labeled c) low in BOD and NH4–N, the aquatic species showed low removal and stress even at the lowest load of COD=2 g m−2 day−1. We cannot say if this is due to the pretreatment itself or the chemical or microbial composition of this leachate. The Stenotaphrum system operated well with this load of leachate c. For untreated leachate (type a and b) the removal and plant growing conditions seemed good at COD=2 g m−2 day−1. For S. secundatum a load of COD=5 g m−2 day−1 operated well. All loads above COD=5 g m−2 day−1 caused low removal and stress, and the green parts of the plants disappeared. Oxygen was, however, consumed throughout the experimental period. For pretreated leachate (type c), the removal of COD were low (−24 to 17%) but good for NH4–N (52–91%). This leachate also experienced high ammonia removal from the beginning of the experiments, probably due to existing consortia of nitrifying bacteria in it. Statistical analysis shows that the S. secundatum and L. minor systems maintained higher oxygen levels than the M. verticellatum and E. crassipes systems, when operated with tap water. For Lemna minor, this may be due to a better capacity for transporting oxygen into the water. With leachate all S. secundatum systems have higher oxygen levels than the aquatic systems, basically because the water content of the soil has been kept well below saturation. S. secundatum shows a significantly lower removal of COD than did the aquatic systems at a loading of COD=2 g m−2 day−1 of raw leachate. There is no significant difference between the systems in the removal of NH4–N at a loading of COD=2 g m−2 day−1 of both types of leachate. E. crassipes has a lower removal of NH4–N than M. verticellatum and S. secundatum at a loading of 5 g m−2 day−1 of COD of both types of leachate. In our experiments, it appears that the amount of free ammonia explains the toxicity of the leachate to the plants. This, however, does not exclude other possible toxic factors.  相似文献   

20.
Abstract

In the present study, the effectiveness of water hyacinth and water lettuce was tested for the phytoremediation of landfill leachate for the period of 15?days. Fifteen plastic containers were used in experimental setup where aquatic plants were fitted as a floating bed with the help of thermo-pole sheet. It was observed that both plants significantly (p?<?0.05/p?<?0.01/p?<?0.001) reduce the physicochemical parameters pH, TDS, BOD, COD and heavy metals like Zn, Pb, Fe, Cu and Ni from landfill leachate. Maximum reduction in these parameters was obtained at 50% and 75% landfill leachate treatment and their removal rate gradually increased from day 3 to day 15 of the experiment. The maximum removal rate for heavy metals such as for Zn (80–90%), Fe (83–87%) and Pb (76–84%) was attained by Eichhornia crassipes and Pistia stratiotes. Value of bioconcentration and translocation factor was less than 1 which indicates the low transport of heavy metals from roots to the above-ground parts of the plants. Both these plants accumulate heavy metals inside their body without showing much reduction in growth and showing tolerance to all the present metals. Therefore, results obtained from the study suggest that these aquatic plants are suitable candidate for the removal of pollution load from landfill leachate.  相似文献   

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