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湿地松针叶挥发油化学成分研究 总被引:12,自引:0,他引:12
采用常压水蒸气蒸馏法提取了湿地松针叶挥发油,得油率为0.19-0.29%。用GC,IR,NMR,GC-MS等方法对该精油进行了定性定量分析,在分出的36个色谱峰中共鉴定出33个化合物,占该精油总量的99.79%,其中含有α-蒎烯,Δ^3-蒈烯,γ-松油烯,乙酸龙脑酯,乙酸匝萜品酯及长叶烯等,含量最多的成分是β-蒎烯(36.536%). 相似文献
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《天然产物研究与开发》2016,(11)
为了考察树龄、虫害与巨尾桉叶油成分的相互关系,更好的开发桉树资源,采用水蒸气蒸馏法提取不同树龄(4~6年生)巨尾桉叶油,用GC-MS法对巨尾桉叶油主要化学成分进行鉴定,分析不同树龄和染虫状态的桉叶油成分变化规律。结果表明,随着树龄增加,桉叶油总量逐年增加;生长年限不同,桉叶油中物质的组成及相对含量存在差异。主要成分相对含量变化情况为:桉油醇、乙酸松油酯含量随树龄逐年上升;d-柠檬烯、α-蒎烯相对含量在4到5年达到峰值,5年后开始下降;莰烯、β-蒎烯和α-松油醇逐年下降。被云斑天牛感染的林地,桉油醇、α-蒎烯、β-蒎烯、莰烯呈相对下降趋势,而d-柠檬烯、α-松油醇、乙酸松油酯的含量上升。 相似文献
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用毛细管气相色谱—质谱—计算机联用技术,毛细管气相色谱和标准品叠加法分析了少官桂(Neocinnamomum delauayi(H.Lec.)Liou)叶精油的化学成分。从分离出的67个色谱峰中鉴定出了41个成分。其中主要成分是樟脑(41.006%),a-蒎烯(6.975%),茨烯(6.967%),β-蒎烯(2.854%),月桂烯(2.494%),柠檬烯(5.064%),乙酸冰片酯(5.404%)和顺式石竹烯(6.613%)。分析结果表明,少官桂叶精油用来生产樟脑是有价值的。 相似文献
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佛手挥发油特征化学成分群GC-MS研究 总被引:2,自引:0,他引:2
目的:分析6个不同产地佛手挥发油的化学成分,确定其特征化学指标成分群.方法:采用水蒸气蒸馏法提取佛手挥发油.运用气相色谱质谱联用技术(GC-MS),结合计算机检索对其化学成分进行分离和鉴定,得到其共有的特征性化学成分群,用色谱峰面积归一化法计算各组分的相对含量.结果:从广东、四川、金华、广西、安徽佛手的挥发油中鉴定16种共有特征成分,按保留时间的先后顺序分别为:α-水芹烯、α-蒎烯、β-蒎烯、β-月桂烯、α-萜品油烯、邻伞花烃、柠檬烯、顺式-β-罗勒烯、反式-β-罗勒烯、γ-萜品烯、γ-萜品油烯、乙酸芳樟酯、顺式-水合桧烯、α-萜品醇、β-柠檬醛、α-柠檬醛,其占总峰面积的的比例大于82.9%;其中柠檬烯和γ-萜品烯是主要成分,两者峰面积占总峰面积的比例大于65%.结论:所建立的特征成分群能充分地袁征佛手挥发油化学组成,可以为佛手挥发油的质量评价提供参考. 相似文献
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不同类型梅花品种挥发性成分的研究 总被引:2,自引:0,他引:2
用GC-MS分析梅花(Prunus mume)5个品种(三轮玉蝶、北京玉蝶、单瓣玉、淡粉和江南朱砂)花朵中的挥发性成分,从中鉴定出45个化合物,其中芳香族化合物是主要成分.不同类型的梅花品种香气成分不同,这些化合物种类和含量的变化导致不同类型的梅花品种花香差异,一些重要的共有成分乙酸己酯、丁子香酚、乙酸苯甲酯和α-蒎烯等化合物的存在是导致梅花品种花香相似的主要原因. 相似文献
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It has been shown that the cultured cells of Digitalis purpruea are capable of transforming progesterone (I) to 5α-pregnane-3,20-dione (II), 5α-pregnan-3β-ol-20-one (III), its glucoside (IV), 5α-pregnane-3β,20α-diol (V), its glucoside (VI), 5α-pregnane-3β,20β-diol (VII), its glucoside (VIII), Δ4-pregnen-20α-ol-3-one (IX), its glucoside (X), Δ-pregnen-20β-ol-3-one (XI) and its glucoside (XII). 5α-Pregnan-3β-ol-20-one glucoside (IV), 5α-pregnane-3β,20α-diol glucoside (VI), 5α-pregnane-3β,20β-diol glucoside (VIII), Δ4-pregnen-20α-ol-3-one glucoside (X) and Δ4-pregnen-20β-ol-3-one glucoside (XII) have been found for the first time as new metabolises by plant tissue cultures. A scheme for the biotransformation of progesterone (I) has been proposed, and the reduction and glucosidation activities distinctly have been observed in these cultured cells. 相似文献
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From fresh Pinus contorta Doug (Coastal) needles four flavonol acylated glucosides and 6-methyl-kaempferol 3-β-D-glucoside were isolated. The three monoacylated glucosides were kaempferol-3-β-D(6-O-p- coumaryl)glucoside, isorhamnetin-3-β-D-(6-O-acetyl)glucoside, quercetin-3-β-D-(p-coumaryl)glucoside and the diacyl compound was kaempferol-3-β-D-(di-p-coumaryl)glucoside. 相似文献
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A new diterpene glucoside was isolated from Isodon parvifolia (Batalin) Hara collected in Sichuan,China. Its structure was established as 7,20-epoxy-ent-kaur-16-ene-lα, 6β,7β, llβ, 15β-pentaol-ll-O-β-D-glucopyranoside(1)by spectroscopic and chemical evidence. 相似文献
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Dixit P Chillara R Khedgikar V Gautam J Kushwaha P Kumar A Singh D Trivedi R Maurya R 《Bioorganic & medicinal chemistry letters》2012,22(2):890-897
One new isoflavone glucoside, caviunin 7-O-[β-d-apiofuranosyl-(1→6)-β-d-glucopyranoside] (10) and a new itaconic derivative, (E)-4-methoxy-2-(3,4-dihydroxybenzylidene)-4-oxobutanoic acid (15) along with series of isoflavones and flavonols with their glucosides (1-9 and 11-14) and a lignan glucoside (16) were isolated from the ethanolic extract of Dalbergia sissoo leaves. The structures of these compounds were established on the basis of IR, UV, (1)H and (13)C NMR, DEPT, COSY, HSQC, HMBC and MS data. All compounds (1-16) were assessed for osteogenic activity in primary calvarial osteoblast cultures. Compounds 1-4 and 10 increased alkaline phosphatase activity and mineralization thus resulting in significant osteogenic activity. 相似文献
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从毛脉酸模根(Rumex gmelini Turcz.)75%乙醇提取物中分离得到1个新色原酮苷和5个已知化合物,应用波谱学方法及文献对照分别鉴定为2,5-dimethyl-7-hydroxychromone-7-O-β-glucopyranoside (1),nepodin-8-O-β-D-glucopyranoside (2),10-hydroxyaloin A (3),10-hydroxyaloin B (4),5-methoxyl-1(3H)-benzofuranone-7-O-β-D-glucopyranoside (5),phenylethyl-O-α-L-arabinopyranosy-(1→6)-O-β-D-glucopyranoside (6). 其中化合物1为新化合物,3~6首次从酸模属中分离得到,化合物2首次从该植物中分离得到. 相似文献
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Three xanthone glycosides, a flavonoid glucoside and a triterpen acid have been isolated from Swertia franchetiana H. Smith (Gentianaceae). One of them is a new xanthone glyco- side and its stucture is established as 1-O-[β-D-xylopyranosyl-(1-6)-β-D-glucopyranosyl] 3, 5-dimethoxyxanthone (Ⅺ), Others are identified as swertianolin, swertisin, mangiferin and oleanolic acid by chemical and spectral means, respectively. 相似文献
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A new neolignan glucoside was isolated from hairy roots of Cichorium intybus. Its structure was determined as (7S, 8R)-3′-demethyl-dehydrodiconiferyl alcohol-3′-O-β-glucopyranoside based on a combination of 1D and 2D NMR techniques and CD data. In addition, further water soluble constituents, including four known phenolic compounds and one known sesquiterpene lactone glucoside, were isolated from the same source. 相似文献
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It has been shown that the cultured cells of Nicotiana tabacum “Bright Yellow” are capable of transforming testosterone to Δ4-androstene-3, 17-dione, 5α-androstan-17β-ol-3-one, 5α-androstane-3β, 17β-diol, its dipalmitate and 3- and 17-monoglucosides, epiandrosterone, its palmitate and glucoside, testosterone glucoside. 5α-Androstane-3β, 17β-diol dipalmitate and 3- and 17-monoglucosides, epiandrosterone palmitate and glucoside, and testosterone glucoside have been found for the first time as metabolites of testosterone in plant systems. Δ4-Androstene-3,17-dione was converted to testosterone. 5α-Androstan-17β-ol-3-one, which has been recognized as an active form of testosterone in mammals, was also detected. It has also been demonstrated that [4-14C]testosterone is actively incorporated in these transformations. 相似文献
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Prasanna K. Dadi Mubeen Ahmad Zulfiqar Ahmad 《International journal of biological macromolecules》2009,45(1):72-79
We have studied the inhibitory effect of five polyphenols namely, resveratrol, piceatannol, quercetin, quercetrin, and quercetin-3-β-d glucoside on Escherichia coli ATP synthase. Recently published X-ray crystal structures of bovine mitochondrial ATP synthase inhibited by resveratrol, piceatannol, and quercetin, suggest that these compounds bind in a hydrophobic pocket between the γ-subunit C-terminal tip and the hydrophobic inside of the surrounding annulus in a region critical for rotation of the γ-subunit. Herein, we show that resveratrol, piceatannol, quercetin, quercetrin, or quercetin-3-β-d glucoside all inhibit E. coli ATP synthase but to different degrees. Whereas piceatannol inhibited ATPase essentially completely (~0 residual activity), inhibition by other compounds was partial with ~20% residual activity by quercetin, ~50% residual activity by quercetin-3-β-d glucoside, and ~60% residual activity by quercetrin or resveratrol. Piceatannol was the most potent inhibitor (IC50 ~14 μM) followed by quercetin (IC50 ~33 μM), quercetin-3-β-d glucoside (IC50 ~71 μM), resveratrol (IC50 ~94 μM), quercitrin (IC50 ~120 μM). Inhibition was identical in both F1Fo membrane preparations as well as in isolated purified F1. In all cases inhibition was reversible. Interestingly, resveratrol and piceatannol inhibited both ATPase and ATP synthesis whereas quercetin, quercetrin or quercetin-3-β-d glucoside inhibited only ATPase activity and not ATP synthesis. 相似文献