Imaging and Characterizing Long-Range Surface Plasmon Polaritons Propagating in a Submillimeter Scale by Two-Color Two-Photon Photoelectron Emission Microscopy

Long-range surface plasmon polaritons (SPPs), which propagate along metal/dielectric interfaces to submillimeter distances in the range of near-infrared (NIR) excitation wavelength, were examined by two-color two-photon photoelectron emission microscopy (2P-PEEM). Interferences between incident NIR photons and SPPs excited by the NIR photons at surface defects were imaged by detecting photoelectrons emitted from a gold surface, assisted by simultaneously irradiated ultraviolet photons which are to overcome the workfunction of the surface. The wavelength of the interference beat depends sensitively on the NIR wavelength. By analyzing the interference beat, the dispersion curve as well as phase and group velocities of SPP’s were experimentally obtained. The results closely match the theoretical one based on the Drude free electron model, indicating that two-color 2P-PEEM is applicable not only to the visualization of NIR-excited SPPs but also to the quantitative analysis of its physical properties. This method will be widely used to observe SPPs for various artificial plasmonic devices.     

Influence of Fabrication Methods of Gold and Silver Layers on Surface Plasmon Polaritons Propagation Length

We present an experimental study of surface plasmon polaritons (SPPs) propagation length (L_SPP) on polycrystalline metal (gold and silver) films, fabricated by evaporation and sputtering techniques on glass substrates. For the excitation of SPPs, polymer grids on the sample surface are used. The SPPs are excited by a He-Ne (633 nm) and the L_SPP are measured by grating-coupling method and the leakage radiation microscopy. Dependence of L_SPP on the film thickness is also investigated. The longer L_SPP is observed with evaporation technique in comparison to the sputtering technique for the silver films. On the other hand, sputtering technique provides longer L_SPP for the gold films. Additionally, atomically flat crystalline gold flakes are also considered for the SPPs evaluation. The L_SPP estimation on these flakes is carried out for light wavelength of 633 and 800 nm.

     

Near-infrared Plasmonic Far-field Nanofocusing Effects with Elongated Depth of Focus based on Hybrid Au–Dielectric–Ag Subwavelength Structures

In this paper, we propose a new far-field nanofocusing lens with elongated depth of focus (DOF) under near-infrared (NIR) wavelength. The surface plasmons can be excited by using the hybrid metal–insulator–metal (MIM) subwavelength structure under the NIR wavelength. The constructive interference of surface plasmons launched by the subwavelength MIM structure can form a nanoscale focus that is modulated by the novel metal grating from the near field to the far field. The numerical simulations demonstrated that a nanoscale focal spot (in plane focal area 0.177λ ²) with elongated DOF (3.358λ) and long focal length (5.084λ) can be realized with reasonably designing parameters of the lens. By controlling the positions of the inner radii of each slit ring and the grating width, the focal length, focal spot, and DOF can be tuned easily. This design method, which can obtain the nanoscale focal spot and micron DOF in far field under NIR illumination, paved the road for utilizing the NIR plasmonic lens in superresolution optical microscopic imaging, optical trapping, biosensing, and complex wavefront/beam shaper.     

Efficient and Directional Excitation of Surface Plasmon Polaritons by Oblique Incidence on Metallic Ridges

For many years, the search for efficient surface plasmon polariton (SPP) excitation mechanisms has been a recurring matter in the development of compact plasmonic devices. In this work, we excited SPPs illuminating a subwavelength metallic ridge with a focused spot to characterize the coupling efficiency by varying the incidence angle of the excitation beam from ??50 to 50°. The intensity distribution of the excited SPPs was measured using leakage radiation microscopy to determine the relative coupling efficiency in the wavelength interval from 740 to 840 nm. We modeled the excitation efficiency as a function of the incidence angle using a simple analytical diffraction model. Two ridges of different width (200 and 500 nm) were used to compare results and validate the model. The experimental results show a higher coupling efficiency at oblique incidence, where the coupling was enhanced by factors of 2× for the 500-nm-wide ridge, and 3× for the 200-nm-wide ridge, as well as unidirectional SPP excitation. The experimental results are in good agreement with the proposed model.     

Correlation Between Surface Charge Distribution and Circular Dichroism of Elementary Planar Nanoparticles

A correlation is observed between surface charge distributions and the circular dichroism (CD) signature of nanoparticles excited by circularly polarized waves. These surface charge distributions arise as a result of charge separation and depend on the polarization of the externally excited light. This correlation can be observed by deriving the surface charge distribution profile of excited localized surface plasmon polaritons (SPPs) in elementary metal nanoparticles under the influence of circularly polarized light. Nanoparticles with strong CD signatures are especially desired for sensing of chiral biomolecules as well as to aid in photochemical catalysis. We also found out that CD signatures can even be induced via angular rotation. This is true for elementary non-rotated nanoparticles which do not possess a CD signature. The use of elementary nanoparticles for sensing poses a huge advantage over complex nanostructures due to the ease of fabrication. The observed CD signature can also be validated in accordance with theory and simulation results.

     

Tunable Multi-Port Surface Plasmon Polariton Excitation with Nanostructures

Surface plasmon polaritons (SPPs) have appealing features such as tighter spatial confinement and higher local field intensity. Manipulation of surface plasmon polaritons on metal/dielectric interface is an important aspect in the achievement of integrated plasmonic circuit beyond the diffraction limit. Here, we introduce a design of pin cushion structure and a holographic groove pattern structure for tunable multi-port SPPs excitation and focusing. Free space light is coupled into SPPs through momentum matching conditions. Both nanostructures are capable of tunably controlling of SPPs depending on the incident polarizations, while the holographic method provides more flexibility of wavelength-dependent excitations. Furthermore, a quantitative method is applied to calculate the efficiencies of excitation for both nanostructures under different conditions, including radially polarized incident beams. These results can work as a guidance and be helpful to further choice of the suitable design strategies for variable plasmonic applications such as beam splitter, on-chip spectroscopy, and plasmonic detectors.     

Directional Excitation of Surface Plasmon Polaritons by Circularly Polarized Vortex Beams

We investigate the excitation of surface plasmon polaritons (SPPs) using a metallic nanoaperture array illuminated by circularly polarized Laguerre-Gaussian (LG) vortex beams. The direction of SPP excitation is tunable by changing the circular polarization and topological charge of LG beams. The left- or right-handed circular polarization determines SPP propagation on either side of the nanoaperture array. Furthermore, varying the topological charge of LG beam will result in beam splitting of SPPs. We also utilize a composite nanoaperture array with different periods to achieve unidirectional excitation of SPPs. The study provides an interesting approach to control the excitation direction of SPPs and may find great applications in SPP generators and optical switches.

     

Coupling Efficiency of Surface Plasmon Polaritons: Far- and Near-Field Analyses

The excitation of surface plasmon polaritons (SPPs) through one-dimentional (1D) metallic (Au) grating on higher refractive index -GaP substrate is investigated. Such grating devices find potential applications in real world, only if the coupling efficiency (η) of a free-space transverse-magnetic plane-wave into a SPPs mode is maximum. A simple and robust technique is used to estimate the η, by simply measuring the transmission through the grating while varying slit width (a) but period (Λ) and the thickness (t) remain fixed. When the wave vector (k ₀ ) of the incident light is matched to that of SPP, highest η is achieved. It is found that Λ/3 < a < Λ/2 yields a maximum η where the intermediate scattering couples more incident energy to SPPs. These gratings are designed in such a way that they support only the fundamental plasmonic mode yielding higher η. Scanning near-field optical measurements also confirm and corroborate the observations of far-field and near-field modeling (COMSOL multiphysics) results.

     

Engineered Metasurface of Gold Funnels for Terahertz Wave Filtering

Surface plasmon polariton (SPP) excitation of the coupled light at small contact area of chromium pillars as the interface of metastructured gold funnel layer and silica medium can be enhanced locally in the gold meta-funnel-structured filter. In the present investigation, the filter is comprised of three layers, namely gold meta-funnels, nano-sized chromium pillars, and silica as the substrate. The incoming infrared (IR) waves, coupled with the excited plasmons at the first and second layers, form an excitation, known as deformed plasmon polariton. Asymmetric distribution of localized SPPs takes place owing to the inherent converging plasmonic feature of the gold funnel structure. The formation of reflection peaks with different magnitudes at different incidence angles of the polarized wave in the spectral characteristics makes the structure prominent for filtering the IR waves. Moreover, the gold meta-funnel-structured filter possesses the additional feature of distinguishing the type of polarized incidence wave. It was found that the transmission remains maximum corresponding to the normal incidence of the TE-polarized waves, whereas the TM-polarized waves over the same wavelength range are almost blocked for any value of incidence angle. The existence of transmission peaks corresponding to the TE waves demonstrates another application of this device as metastructured polarizer filter.     

Excitation of Multiple Surface Plasmon-Polaritons by a Metal Layer Inserted in an Equichiral Sculptured Thin Film

Excitation of multiple surface plasmon-polaritons (SPPs) by an equichiral sculptured thin film with a metal layer defect was studied theoretically in the Sarid configuration, using the transfer matrix method. Multiple SPP modes were distinguished from waveguide modes in optical absorption for p-polarized plane wave. The degree of localization of multiple SPP waves was investigated by calculation of the time-averaged Poynting vector. The results showed that the long-range and short-range SPP waves can simultaneously be excited at both interfaces of metal core in this proposed structure which may be used in a broad range of sensing applications.     

Propagation Properties of Nanoscale Three-Dimensional Plasmonic Waveguide Based on Hybrid of Two Fundamental Planar Optical Metal Waveguides

In this paper, a nanoscale three-dimensional plasmonic waveguide (TDPW), created by depositing an Ag stripe on a SiO₂ layer with an Ag substrate, is introduced and theoretically investigated at visible and telecom wavelengths. By applying the effective index method and finite-difference time-domain numerical simulations, the authors find that the propagation properties of surface plasmon polaritons (SPPs) in the TDPW, including the propagation length and beam width, are mainly decided by the core (the SiO₂ layer just under the Ag stripe) itself, due to the much stronger localization of SPPs in the core than in the two side claddings (the SiO₂ layer without the covered Ag stripe). And propagating SPPs in the TDPW are strongly confined in the core region, even with a very small waveguide cross section. Furthermore, based on the stronger localization of propagation SPPs in the TDPW, two kinds of bending waveguides, oblique bending and 90° circular bending waveguides, are also investigated. For wavelength of 1550 nm, the 90° circular bending guide with a minimum radius as small as 2.6 μm show nearly zero radiation loss, even with a small waveguide cross section of 70?×?80 nm². The proposed TDPW is suitable for planar integration and provides a possible way for constructing various nanoscale counterparts of conventional integrated devices such as splitter, resonator, sensor, and optical switch.     

Tuning Optical Discs for Plasmonic Applications

We present simple physical and chemical procedures that allow tuning and modification of the topography of gratings present in optical storage discs into geometries optimal for grating coupled plasmon resonance excitation. After proper metal coating, the tuned surfaces exhibit sharp plasmon resonances that can be excited at wavelengths ranging from 260 nm to over 2.7 μm with relatively high quality factors. As an immediate exemplary application, use of such optimized gratings in aqueous medium for refractive index measurement is demonstrated.     

Radiative decay engineering 7: Tamm state-coupled emission using a hybrid plasmonic–photonic structure

There is a continuing need to increase the brightness and photostability of fluorophores for use in biotechnology, medical diagnostics, and cell imaging. One approach developed during the past decade is to use metallic surfaces and nanostructures. It is now known that excited state fluorophores display interactions with surface plasmons, which can increase the radiative decay rates, modify the spatial distribution of emission, and result in directional emission. One important example is surface plasmon-coupled emission (SPCE). In this phenomenon, the fluorophores at close distances from a thin metal film, typically silver, display emission over a small range of angles into the substrate. A disadvantage of SPCE is that the emission occurs at large angles relative to the surface normal and at angles that are larger than the critical angle for the glass substrate. The large angles make it difficult to collect all of the coupled emission and have prevented the use of SPCE with high-throughput and/or array applications. In the current article, we describe a simple multilayer metal–dielectric structure that allows excitation with light that is perpendicular (normal) to the plane and provides emission within a narrow angular distribution that is normal to the plane. This structure consists of a thin silver film on top of a multilayer dielectric Bragg grating, with no nanoscale features except for the metal or dielectric layer thicknesses. Our structure is designed to support optical Tamm states, which are trapped electromagnetic modes between the metal film and the underlying Bragg grating. We used simulations with the transfer matrix method to understand the optical properties of Tamm states and localization of the modes or electric fields in the structure. Tamm states can exist with zero in-plane wavevector components and can be created without the use of a coupling prism. We show that fluorophores on top of the metal film can interact with the Tamm state under the metal film and display Tamm state-coupled emission (TSCE). In contrast to SPCE, the Tamm states can display either S or P polarization. The TSCE angle is highly sensitive to wavelength, which suggests the use of Tamm structures to provide both directional emission and wavelength dispersion. Metallic structures can modify fluorophore decay rates but also have high losses. Photonic crystals have low losses but may lack the enhanced light-induced fields near metals. The combination of plasmonic and photonic structures offers the opportunity for radiative decay engineering to design new formats for clinical testing and other fluorescence-based applications.     

Plasmonic Band Gap: Role of the Slit Width in 1D Metallic Grating on Higher Refractive Index Substrate

This paper reports the excitation of surface plasmon polaritons (SPPs) and associated plasmonic band gap (PBG) while using TM plane wave interacting with 1D metallic grating on higher refractive index GaP substrate. A simple method is introduced to estimate the PBG which is crucial for many plasmonic devices. The PBG is estimated by measuring the transmission spectra obtained through the plasmonic grating structures when slit width is varied while periodicity and the thickness of the gold (Au) film remained fixed. The PBG is observed for the grating devices whose slit width is less than one third of the periodicity which is caused by the presence of a higher plasmonic mode. The PBG is absent for the grating device whose slit width is slightly less than half and greater than one third of the periodicity. Such grating devices support only a fundamental plasmonic mode because the profile/shape of the slit in the grating device is more like a sinusoidal nature. Furthermore, such grating offers intermediate scattering to the incident light and the SPP as well which in turn couple more incident energy to the SPPs. Far-field modelling results also support the results obtained through experiment.

     

One Dimensional Plasmonic Grating: High Sensitive Biosensor

We report a simple 1D grating device fabrication on ～50 nm gold (Au) film deposited on glass, which is employed as a high performance refractive index (RI) sensor by exploiting the surface plasmon polaritons (SPP) excited by the grating device along the Au/analyte interface. A finite element analysis (FEA) method is employed to maximize the sensitivity of the sensor for a fixed period and thickness of a gold film and its close correspondence with experiment has given the insight for high sensitivity and enhanced transmission. Significantly, in the context of economic design and performance, it is shown that an optimally designed and fabricated 1D grating can be as sensitive as 524 nm/RIU (linearity RI?=?1.33303 to 1.47399), which is remarkably higher than existing reports operating in a similar wavelength region.     

Extraordinary Optical Transmission Performances of Nanosandwiched Grating for Wideband Multi-Function Integration

In this paper, we present a peculiar metal-dielectric-metal (MDM) nanosandwich grating structure that can achieve extraordinary optical transmission performances at normal incidence in the ultraviolet-visible-near infrared (UV-VIS-NIR) regions. The proposed structure shows three obvious spectrum characteristics: it can obtain high transmittance up to 80 % in NUV region and efficiently blocking visible wavelengths for transverse-magnetic (TM) polarized incidence; a broadband NIR polarizer can be inspired in the wavelength range from 950 to 1400 nm; more surprisingly, these performances do not deteriorated until 30° tilting angle. Compared to other grating structures with single metal overlayer, it shows wider band-stop characteristics and higher broadband transmission transmittance and extinction ratio (ER) in the investigated wavebands. We analyze the underlying physical mechanism by using numerical simulation, which is primarily attributed to metal ultraviolet transparency, surface plasmon polariton (SPP) at metal/dielectric interface, Fabry–Perot (FP)-like cavity mode within this dielectric grating, and optical magnetic resonance especially in the dielectric interlayer of the MDM sandwiched structure. This structure is very important for developing high-performance subwavelength multifunctional integrated optical devices.     

Luminescence characterization of KBaPO4:RE (RE = Sm3+,Eu3+,Dy3+) phosphors

KBaPO₄ luminescent powdered phosphors doped with rare earth elements (RE = Sm³⁺,Eu³⁺,Dy³⁺) were successfully synthesized using a wet chemical method to identify the most suitable phosphor for solid‐state lighting based on the measurement of their emission spectra at excitation wavelengths. The X‐ray diffraction pattern of the as‐prepared KBaPO₄ was well matched with its standard JCPDS file no. 330996, indicating the formation of the desired compound. Scanning electron microscopy images revealed irregular morphology, the material crystallized particles aggregated and were non‐uniform with particle sizes ranging from 1 to 100 μm. Photoluminescence excitation and emission spectra clearly indicated that the phosphor containing the Sm³⁺‐activated KBaPO₄ phosphors could be efficiently excited at 403 nm and exhibited an emission mainly including two wavelength peaks at 559 nm and 597 nm. The phosphor containing the Eu³⁺‐activated KBaPO₄ phosphors could be efficiently excited at 396 nm and exhibited a bright red emission mainly including two wavelength peaks at 594 nm and 617 nm. The phosphor containing the Dy³⁺‐activated KBaPO₄ phosphors could be efficiently excited at 349 nm and exhibited wavelength peaks at 474 nm and 570 nm.     

Surface Phonon Resonance Assisted Refractive Index Sensing in Mid-Infrared Wavelength Range

We propose a highly sensitive refractive index sensor based on the surface phonon resonance (SPhR) in the mid-IR spectral range. Surface phonon polaritons (SPhPs) are formed on polar dielectrics such as SiC in mid-IR wavelength range and can be excited with the help of a metallic grating at specific wavelength termed as resonance wavelength. The resonance wavelength of SPhP is significantly affected by the refractive index of the analyte medium placed over the grating. This forms the basis of a refractive index sensor. We have numerically evaluated the performance of such an SPhP-based refractive index sensor by using rigorous coupled wave analysis (RCWA) in terms of sensitivity, detection accuracy, and quality factor. The quality factor and detection accuracy of the sensor formed on SiC substrate are found to be 225.1 RIU^–1 (inverse of refractive index unit) and 6.75, respectively. We have also extended the study for other polar dielectric substrates cBN and GaN and observed considerable enhancement in the performance of the sensor for GaN. The values of quality factor and detection accuracy could be increased to 361.2 RIU^–1 and 10.84, respectively, by using GaN substrate. The proposed sensor finds applications in refractive index sensing of liquids and biomolecules having refractive index in the range 1.33–1.36.

     

Effect of a strong monochromatic electromagnetic wave with circular polarization on one-dimensional wake waves in plasma

A study is made of the excitation of wake waves by a one-dimensional bunch of charged particles in an electron plasma in the presence of an intense monochromatic pump wave with circular polarization. In the main state (in the absence of a bunch), the interaction between a pump wave and a plasma is described by the Maxwell equations and the nonlinear relativistic hydrodynamic equations for a cold plasma. The excitation of linear waves by a one-dimensional bunch is investigated against a cold plasma background. It is shown that, in a certain range of the parameter values of the bunch, pump wave, and plasma, the amplitude of the excited transverse waves grows as the energy of the bunch particles increases until the relativistic factor of the bunch reaches a certain threshold value above which the transverse wave amplitude becomes essentially independent of the bunch particle energy and grows as the intensity and frequency of the pump wave increase. The amplitude and wavelength of the longitudinal field, which is shown to depend weakly on the energy of the bunch particles, grows with increasing the pump wave intensity.     

Efficient Surface Plasmon Polariton Excitation with the Beam Generated by Micro Triangular Prism

The optical beam generated by a micro triangular prism is presented to excite surface plasmon polaritons (SPPs) on a single silver nano slit. The electromagnetic fields generated by the micro triangular prism and the excited surface plasmon polaritons are simulated with finite-difference time-domain method. Compared with directly normal incident beam, the efficiency of SPPs’ excitation with the beam generated by the micro triangular prism is highly improved.