In this paper, we have inspected the optical characteristics of one-dimensional periodic structure (1DPS) of TiO2 and MgF2 dielectric materials with defect layer of liquid crystal (LC) sandwiched with two silver layers, i.e., (TiO2|MgF2)3|Ag|LC|Ag|(TiO2/MgF2)3 using transfer matrix method (TMM). The optical tunable properties of considered periodic structures investigated at different incident angles and temperatures for TE and TM modes. Our study shows that absorption peak of 1DPS varies with incident angle and temperature. The defect layer (Ag-LC-Ag), sandwiched LC within two metallic (Ag) layers, exhibits the surface plasmon waves at the metal LC interfaces. The effect of surface plasmon waves can be better understand through the optical sensing property of such defect periodic structure. The detailed study concludes that such a type of one-dimensional periodic structure (1DPS) may be useful to design a tunable sensor and monochromatic filter.
相似文献Thin films with tunable optical properties from yellow to metallic were prepared from a monolayer coating of silver nanoparticles (AgNP) onto a polyelectrolyte multilayer (PEM) thin film. The AgNP were synthesized using various concentrations of stabilizing polyelectrolytes leading to a competitive adsorption concept in which AgNP compete with excess polyelectrolytes to coat the cationic PEM top layer. The AgNP were synthesized by chemical reduction of Ag salts using poly(styrene 4-sulfonic acid-co-maleic acid) (PSS-co-MA) as stabilizing agent to produce nanoparticles coated with both a strong acid (sulfonic) and a weak acid (carboxylic) moiety. Although all the nanoparticle solutions displayed a characteristic bright yellow due to the localized surface plasmon band around 420 nm, the monolayer films of nanoparticles obtained after dipping displayed striking different optical properties. When using a high PSS-co-MA content in the solution, a pale-yellow film was obtained which color shifted to orange and metallic when the capping concentration was decreased from 0.25 to 0.001 mM. The optical properties of the AgNP film could be further changed by galvanic replacement of the Ag with gold ions to produce a gold monolayer. These results are interesting to produce surface with tunable catalytic properties, tunable optical properties, or to be used as primer for the metallization of polymeric surfaces.
相似文献We demonstrate the optical response of metal nanoparticles and their interaction with organic-inorganic perovskite (methyl ammonia lead halide (CH3NH3PbI3)) environment using discrete dipole approximation (DDA) simulation technique. Important optical properties like absorption, scattering, and electric field calculations for metal nanoparticle using different geometry have been analyzed. The metal nanoparticles embedded in the perovskite media strongly support surface plasmon resonances (SPRs). The plasmonic interaction of metal nanoparticles with perovskite matrix is a strong function of MNP’s shape, size, and surrounding environment that can manipulate the optical properties considerably. The cylindrical shape of MNPs embedded in perovskite environment supports the SPR which is highly tunable to subwavelength range of 400–800 nm. Wide range of particle sizes has been selected for Ag, Au, and Al spherical and cylindrical nanostructures surrounded by perovskite matrix for simulation. The chosen hybrid material and anisotropy of structure together make a complex function for resonance shape and width. Among all MNPs, 70-nm spherical silver nanoparticle (NP) and cylindrical Ag NP having diameter of 50 nm and length of 70 nm (aspect ratio 1.4) generate strong electric field intensity that facilitates increased photon absorption. The plasmonic perovskite interaction plays an important role to improve the absorption of photon inside the thin film perovskite environment that may be applicable to photovoltaics and photonics.
相似文献Digital fabrication is revolutionizing architecture, enabling the construction of complex and multi-functional building elements. Multi-functionality is often achieved through material reduction strategies such as functional or material hybridization. However, these design strategies may increase environmental impacts over the life cycle. The integration of functions may hinder the maintenance and shorten the service life. Moreover, once a building element has reached the end of life, hybrid materials may influence negatively its recycling capacity. Consequently, the aim of this paper is to analyze the influence of multi-functionality in the environmental performance of two digitally fabricated architectural elements: The Sequential Roof and Concrete-Sandstone Composite Slab and to compare them with existing standard elements.
MethodsA method based on the life-cycle assessment (LCA) framework is applied for the evaluation of the environmental implications of multi-functionality in digital fabrication. The evaluation consists of the comparison of embodied impacts between a multi-functional building element constructed with digital fabrication techniques and a conventional one, both with the same building functions. Specifically, the method considers the lifetime uncertainty caused by multi-functionality by considering two alternative service life scenarios during the evaluation of the digitally fabricated building element. The study is extended with a sensitivity analysis to evaluate the additional environmental implications during end-of-life processing derived from the use of hybrid materials to achieve multi-functionality in architecture.
Results and discussionThe evaluation of two case studies of digitally fabricated architecture indicates that their environmental impacts are very sensitive to the duration of their service life. Considering production and life span phases, multi-functional building elements should have a minimum service life of 30 years to bring environmental benefits over conventional construction. Furthermore, the case study of Concrete-Sandstone Composite Slab shows that using hybrid materials to achieve multi-functionality carries important environmental consequences at the end of life, such as the emission of air pollutants during recycling.
ConclusionsThe results from the case studies allow the identification of key environmental criteria to consider during the design of digitally fabricated building elements. Multi-functionality provides material efficiency during production, but design adaptability must be a priority to avoid a decrease in their environmental performance. Moreover, the high environmental impacts caused by end-of-life processing should be compensated during design.
相似文献Exploring hybrid gap surface plasmon polariton waveguides (HGSPPWs) is an important milestone in developing the next-generation, nanoscale integrated photonic circuit technology. To advance their potential applications, HGSPPWs are required to have tunable capability, highly reliable, simple fabrication process, and feasible integration. In this paper, we propose two tunable HGSPPWs fulfilling the requirements. The proposed HGSPPWs consist of a metallic wedge laterally coupled with a dielectric waveguide. The modal characteristics of HGSPPWs are investigated at the optical telecommunication wavelength, which shows the modal characteristics could be effectively controlled by tuning the key geometry parameters and structure of HGSPPWs. The propagation length could achieve the centimeter scale while maintaining the propagation mode size at the deep-subwavelength scale (~ λ2/105). The studies on fabrication tolerance and waveguide crosstalk show their robust property for practical implementations. The effective tunable mechanism is also proposed and studied, which shows remarkable feasibility to realize multifunctional plasmon-based photonic components. Compared with the conventional HGSPPWs, the proposed HGSPPWs exhibit superior features in ultralow loss deep-subwavelength light guiding, are highly reliable, and are easy to integrate.
相似文献Introduction
An optical resonator efficiently confines light at specific wavelengths, known as the resonant wavelengths of the device. 1-2 The common figure of merit for these optical resonators is the quality factor or Q. This term describes the photon lifetime (τo) within the resonator, which is directly related to the resonator''s optical losses. Therefore, an optical resonator with a high Q factor has low optical losses, long photon lifetimes, and very low photon decay rates (1/τo). As a result of the long photon lifetimes, it is possible to build-up extremely large circulating optical field intensities in these devices. This very unique property has allowed these devices to be used as laser sources and integrated biosensors.10A unique sub-class of resonators is the whispering gallery mode optical microcavity. In these devices, the light is confined in circular orbits at the periphery. Therefore, the field is not completely confined within the device, but evanesces into the environment. Whispering gallery mode optical cavities have demonstrated some of the highest quality factors of any optical resonant cavity to date.9,11 Therefore, these devices are used throughout science and engineering, including in fundamental physics studies and in telecommunications as well as in biodetection experiments. 3-7,12Optical microcavities can be fabricated from a wide range of materials and in a wide variety of geometries. A few examples include silica and silicon microtoroids, silicon, silicon nitride, and silica microdisks, micropillars, and silica and polymer microrings.13-17 The range in quality factor (Q) varies as dramatically as the geometry. Although both geometry and high Q are important considerations in any field, in many applications, there is far greater leverage in boosting device performance through Q enhancement. Among the numerous options detailed previously, the silica microsphere and the silica microtoroid resonator have achieved some of the highest Q factors to date.1,9 Additionally, as a result of the extremely low optical loss of silica from the visible through the near-IR, both microspheres and microtoroids are able to maintain their Q factors over a wide range of testing wavelengths.18 Finally, because silica is inherently biocompatible, it is routinely used in biodetection experiments.In addition to high material absorption, there are several other potential loss mechanisms, including surface roughness, radiation loss, and contamination loss.2 Through an optimization of the device size, it is possible to eliminate radiation losses, which arise from poor optical field confinement within the device. Similarly, by storing a device in an appropriately clean environment, contamination of the surface can be minimized. Therefore, in addition to material loss, surface scattering is the primary loss mechanism of concern.2,8In silica devices, surface scattering is minimized by using a laser reflow technique, which melts the silica through surface tension induced reflow. While spherical optical resonators have been studied for many years, it is only with recent advances in fabrication technologies that researchers been able to fabricate high quality silica optical toroidal microresonators (Q>100 million) on a silicon substrate, thus paving the way for integration with microfluidics.1The present series of protocols details how to fabricate both silica microsphere and microtoroid resonant cavities. While silica microsphere resonant cavities are well-established, microtoroid resonant cavities were only recently invented.1 As many of the fundamental methods used to fabricate the microsphere are also used in the more complex microtoroid fabrication procedure, by including both in a single protocol it will enable researchers to more easily trouble-shoot their experiments. 相似文献In this study, we present a high-performance tunable plasmonic absorber based on metal-insulator-metal nanostructures. High absorption is supported over a wide range of wavelengths, which is retained well at a very wide range of incident angles too. The coupling process occurs with high absorption efficiency of ∼ 99% by tuning the thickness of the dielectric layer. In addition, a complex trapezoidal nanostructure based on simple metal-insulator-metal structures by stacking different widths of Cu strip-nanostructures in the vertical direction has been put forward to enhance light absorption based on selective absorption. A trapezoidal sample has been designed with a solar absorption as high as 95% at wavelengths ranging from 300 nm to 2000 nm for different operating temperatures. Furthermore, the optical absorber has a very simple geometric structure and is easy to integrate into complex photonic devices. Perfect absorption and easy fabrication of the metal-insulator-metal structure make it an attractive device in numerous photonic applications.
相似文献Plasmonic nanoparticles (NPs) like silver (Ag) strongly absorb the incident light and produce enhanced localized electric field at the localized surface plasmon resonance (LSPR) frequency. Enormous theoretical and experimental research has focused on the plasmonic properties of the metallic nanoparticles with sizes greater than 10 nm. However, such studies on smaller sized NPs in the size range of 3 to 10 nm (quantum-sized regime) are sparse. In this size regime, the conduction band of the metal particles discretizes, thus altering plasmon properties of the NPs from classical to the quantum regime. In this study, plasmonic properties of the spherical Ag NPs in size range of 3 to 20 nm were investigated using both quantum and classical modeling to understand the importance of invoking quantum regime to accurately describing their properties in this size regime. Theoretical calculations using standard Mie theory were carried out to monitor the LSPR peak shift and electric field enhancement as a function of the size of the bare plasmonic nanoparticle and the refractive index (RI) of the surrounding medium. Comparisons were made with and without invoking quantum regime. Also, the optical properties of metallic NPs conjugated with a chemical ligand using multi-layered Mie theory were studied, and interesting trends were observed.
相似文献In this paper, Tamm plasmons with topological insulators in a composite structure consisting of Bi2Se3, spacer layer, and one-dimensional photonic crystal (1DPC) have been demonstrated theoretically. The perfect absorption has been realized in the terahertz regime because of the optical Tamm states (OTSs) excited at the interface between Bi2Se3 and 1DPC. The perfect absorption can be realized for both TE and TM waves, and it is noted that the perfect absorption can be obtained at any incident angle by simultaneously changing the wavelength of incident light for TE-polarizations. Moreover, the perfect absorption can be realized at different wavelengths with the change of the chemical potential and the thickness of Bi2Se3. The thickness and the dielectric constant of the spacer layer will also play a vital role in the performance of the perfect absorber. Especially, the multichannel perfect absorption phenomenon can be achieved by choosing the appropriate thickness of the spacer layer. This tunable and multichannel terahertz perfect absorber has great application potential in the solar energy, photodetection, and THz biosensor.
相似文献Noble metal nanoparticles (NPs) have attracted much attention due to their unique physical and chemical properties such as tunable surface plasmonics, high-efficiency electrochemical sensing, and enhanced fluorescence. We produced two biosensor chips consisting of Ag@Au bimetallic nanoparticles (BNPs) on a carbon thin film by simple RF-sputtering and RF-plasma-enhanced chemical vapor co-deposition. We deposited Au NPs with average size of 4 nm (Au1 NPs) or 11 nm (Au2 NPs) on a sensor chip consisting of Ag NPs with mean size of 15 nm, and we investigated the effect of shell size (Au NPs) on the chemical activities of the resulting Ag@Au1 BNPs and Ag@Au2 BNPs. We estimated the average size and morphology of Ag@Au BNPs by scanning electron microscopy (SEM) and atomic force microscopy (AFM) images. X-ray diffraction (XRD) patterns revealed that Ag NPs and Au NPs had face-centered cubic (FCC) structure. We studied aging of the biosensor chips consisting of Ag@Au BNPs by localized surface plasmon resonance (LSPR) spectroscopy for up to 3 months. UV–visible aging of the prepared samples indicated that Ag@Au1 BNPs, which corresponded to Ag NPs covered with smaller Au NPs, were more chemically active than Ag@Au2 BNPs. Furthermore, we evaluated changes in the LSPR absorption peaks of Ag@Au1 BNPs and bare Ag NPs in the presence of a DNA primer decamer at fM concentrations, to find that Ag@Au1 BNPs were more sensitive biosensor chips within a short response time as compared to bare Ag NPs.
相似文献We present the optical characteristics of 10-μm-thick crystalline Si wafers with an Ag heptamer nanocluster (NC) array, using a finite-difference time-domain method. The anti-reflection properties of the Ag NC array were more pronounced at long wavelengths, with respect to a monomer array, resulting in significantly enhanced optical absorption in the underlying Si wafer. The scattering cross-section spectra of the NC on the Si wafer exhibited one broad peak with a kink, whereas those in air showed two broad peaks and a sharp Fano dip between them. The high refractive index Si wafer weakened the near-field coupling between particles in the NCs, which modified the optical cross-sections of the Ag NC more drastically than those of the Ag monomer. Therefore, the implementation of the NC nanoantennae for Si-based optoelectronic devices requires careful consideration of the substrate effects.
相似文献In this article, we demonstrate a tunable ultra-broadband metamaterial absorber (TUMA) in terahertz (THz) band which is based on the multilayered structure composed of an Au reflective layer, polyimide dielectric layers, and vanadium dioxide (VO2) periodic structures, respectively. We gain the tunable absorption spectra because of the room temperature phased-changed character of VO2. The relative bandwidth reaches to 81.2% and the absorption rate is over 90% at the frequency range of 1.63–3.86 THz when the temperature (t1) is 350 K, but when t1 = 300 K, the presented absorber is acted as a reflector whose absorption is small besides the frequency points of 9.75 THz and 9.81 THz. For the sake of comprehending the physical mechanism in-depth, the electric field (E-field) diagrams, the surface current distributions and the power loss density (PLD) of the TUMA are investigated. The influences of structural arguments and incident angle (θ) on the absorption are also analyzed. The emulated consequences show that the absorption spectrum can be regulated by changing structural parameters and incident angle and the tunable absorption regions can be obtained by altering the external temperature.
相似文献A new photonic crystal fiber (PCF)–based, hollow-core, optical waveguide is proposed and numerically investigated to quickly identify numerous species of cancerous cells in the human body. Typical and cancerous cells have different refractive indices (RIs), and via this characteristic, the other important optical parameters are evaluated. The guiding properties of this proposed cancer cell sensor are analyzed in the COMSOL Multiphysics environment which used the finite element method as mathematical tool to solve differential equations. Furthermore, to ensure the highest simulation accuracy, extremely fine mesh elements are introduced. The simulation studies confirm that the proposed sensor, at 2.5 THz, achieves an extremely high relative sensitivity of almost 98% with negligible loss (< 0.025 dB/cm). Furthermore, a high numerical aperture (NA) and spot size, with low modal area, enhance the propagation characteristics of the sensor to a new height. The sensor’s physical structure is very simple so that it can be easily fabricated with modern fabrication technology. Thus, it seems that this sensor will open a new door in the field of detecting and diagnosing different cancer cells.
相似文献