Tuning the Dipolar Plasmon Hybridization of Multishell Metal-Dielectric Nanostructure: Gold Nanosphere in a Gold Nanoshell

Because of the interaction between dipole resonances of the inner gold sphere and the outer gold shell, gold-dielectric-gold multishells with sub-50 nm diameter may at most have three hybridization modes of surface plasmon resonance (SPR). Theoretical calculations based on quasi-static theory indicate that there are blending and splitting of SPR bands in the absorption spectra, which makes the number of absorption peak tunable by changing the radius of inserted gold sphere, thickness of gold shell, dielectric constant of middle dielectric shell or outer environment. The two absorption peaks at longer wavelength, which correspond to the hybridization from the bonding shell plasmon and the sphere plasmon, are usually intense and well tunable. The absorption peak at shorter wavelength, which corresponds to the symmetric coupling between the anti-bonding shell plasmon and the sphere plasmon, is relative weak and only occurs with large dielectric constant of the middle shell, small dielectric constant of the outer surrounding, large inner radius of the gold shell, and small radius of the inner gold sphere. Furthermore, the physical origin of these plasmon hybridizations in gold-dielectric-gold multishells nanostructure has also been illuminated by analyzing the local electric field distributions.     

Investigation of the Plasmonic Interaction of Gold Nanoparticles Toward Plasmonic Photothermal Therapeutics

Plasmonic interaction of nanoparticles located in close proximity, embedded in breast tissue, is simulated for estimating the optical characteristics like optical absorption cross-section, plasmonic wavelength as well as full-width half maxima (FWHM). The computations are done for the monomers, homodimers, and heterodimers of spherical and rod-shaped gold nanoparticles considering various interparticle spacings for gold nanospheres and the interparticle spacing as well as the orientation for gold nanorods (GNRs). The results indicate that for the spherical dimer, with the change in interparticle spacing from 1 to 20 nm, the peak absorption cross-section decreases by 43%. Whereas for the GNRs, the absorption cross-section increases/decreases, within 9–18%, depending on the homodimer or heterodimer configuration. Furthermore, secondary peaks for the absorption cross-section are obtained within wavelengths of 630–940 nm due to antibonding modes for GNR heterodimers. For GNR heterodimer located end-to-end, this secondary peak for the absorption cross-section appears at 780 nm irrespective of interparticle spacing within 1–5 nm. The absorption coefficient is considerably dependent on the configuration and proximity of GNRs located within the tissue. While FWHM is not significantly influenced by GNRs configuration and interparticle spacing. For interparticle spacing from 1 to 20 nm, the plasmonic wavelength shifts by 38 nm for the spherical dimer and by 35–86 nm for various GNR dimers. The findings of this study are useful for plasmonic photothermal therapeutics as the heat generation is governed by the resulting absorption cross-section due to plasmonic coupling of the closely spaced and different orientations of the nanoparticles.

     

Buried Effects of Surface Plasmon Resonance Modes for Periodic Metal–Dielectric Nanostructures Consisting of Coupled Spherical Metal Nanoparticles with Cylindrical Pore Filled with a Dielectric

We numerically investigate the buried effects of surface plasmon resonance (SPR) modes for the periodic silver-shell nanopearl dimer (PSSND) array and their solid counterparts with different buried depths in a silica substrate by means of finite element method with three-dimensional calculations. The investigated PSSND array is an important novel geometry for plasmonic metal nanoparticles (MNPs), combining the highly attractive nanoscale optical properties of both metallic nanoshell and cylindrical pore filled with a dielectric. Numerical results for SPR modes corresponding to the effects of different illumination wavelengths, absorption spectra, pore–dielectric, electric field components and total field distribution, charge density distribution, and the model of the induced local field or an applied field of the PSSND array are reported as well. It can be found that the buried MNPs with cylindrical pore filled with a dielectric in a substrate exhibit tunable SPR modes corresponding to the bonding and antibonding modes that are not observed for their solid counterparts.     

Resonant Broadband Field Enhancement in Cylindrical Plasmonic Structure Surrounded by Perovskite Environment

We demonstrate the optical response of metal nanoparticles and their interaction with organic-inorganic perovskite (methyl ammonia lead halide (CH₃NH₃PbI₃)) environment using discrete dipole approximation (DDA) simulation technique. Important optical properties like absorption, scattering, and electric field calculations for metal nanoparticle using different geometry have been analyzed. The metal nanoparticles embedded in the perovskite media strongly support surface plasmon resonances (SPRs). The plasmonic interaction of metal nanoparticles with perovskite matrix is a strong function of MNP’s shape, size, and surrounding environment that can manipulate the optical properties considerably. The cylindrical shape of MNPs embedded in perovskite environment supports the SPR which is highly tunable to subwavelength range of 400–800 nm. Wide range of particle sizes has been selected for Ag, Au, and Al spherical and cylindrical nanostructures surrounded by perovskite matrix for simulation. The chosen hybrid material and anisotropy of structure together make a complex function for resonance shape and width. Among all MNPs, 70-nm spherical silver nanoparticle (NP) and cylindrical Ag NP having diameter of 50 nm and length of 70 nm (aspect ratio 1.4) generate strong electric field intensity that facilitates increased photon absorption. The plasmonic perovskite interaction plays an important role to improve the absorption of photon inside the thin film perovskite environment that may be applicable to photovoltaics and photonics.

     

Plasmonic Properties of Silver Nanoparticles on Two Substrates

In this paper, we examine the plasmonic properties of silver nanoparticles, with an emphasis on the sensitivity of the extinction spectra on the supporting substrate: silica (SiO₂) microsphere and indium tin oxide (ITO) coated glass slide, on which silver particles are deposited electroless and electrochemically, respectively. The microstructures and phases of these nanoparticles are characterized by transmission electron microscopy, field emission electron microscopy and X-ray diffraction analysis. The surface plasmon resonance (SPR) properties which are experimentally measured in the ultraviolet-visible-near infrared spectral region are compared to electrodynamics calculations based on the discrete dipole approximation. A wide SPR band ranging from 400 to 800 nm is observed for the silver nanoparticles on a silica microsphere, which is similar to the plasmon resonance characteristics of metal nanoshells. The SPR of a conducting substrate, however, has an effect on the plasmonic properties of silver nanoparticles at longer wavelength.      

Self-Referencing Plasmonic Array Sensors

A self-referencing plasmonic platform is proposed and analyzed. By introducing a thin gold layer below a periodic two-dimensional nano-grating, the structure supports multiple modes including localized surface plasmon resonance (LSPR), surface plasmon resonance (SPR), and Fabry-Perot resonances. These modes get coupled to each other creating multiple Fano resonances. A coupled mode between the LSPR and SPR responses is spatially separated from the sensor surface and is not sensitive to refractive index changes in the surrounding materials or surface attachments. This mode can be used for self-referencing the measurements. In contrast, the LSPR dominant mode shifts in wavelength when the refractive index of the surrounding medium is changed. The proposed structure is easy to fabricate using conventional lithography and electron beam deposition methods. A bulk sensitivity of 429 nm/RIU is achieved. The sensor also has the ability to detect nanometer thick surface attachments on the top of the grating.

     

Surface Plasmon Coupling Effect of Gold Nanoparticles with Different Shape and Size on Conventional Surface Plasmon Resonance Signal

The labeling strategy with gold nanoparticles for the conventional surface plasmon resonance (SPR) signal enhancement has been frequently used for the sensitive determination of small molecules binding to its interaction partners. However, the influence of gold nanoparticles with different size and shape on SPR signal is not known. In this paper, three kinds of gold nanoparticles, namely nanorods, nanospheres, and nanooctahedrons with different size, were prepared and used to investigate their effects on the conventional SPR signal at a fixed excitation wavelength 670 nm. It was found that the SPR signal (i.e., resonant angle shift) was varied with the shapes and sizes of gold nanoparticles in suspension at a fixed concentration due to their different plasmon absorbance bands. For gold nanorods with different longitudinal absorbance bands, three conventional SPR signal regions could be clearly observed when the gold nanorod suspensions were separately introduced onto the SPR sensor chip surface. One region was the longitudinal absorbance bands coinciding with or close to the SPR excitation wavelength that suppressed the SPR angle shift. The second region was the longitudinal absorbance bands at 624 to 639 and 728 to 763 nm that produced a moderate increase on the SPR resonant angle shift. The third region was found for the longitudinal absorbance bands from 700 to 726 nm that resulted in a remarkable increase in the SPR angle shift responses. This phenomenon can be explained on the basis of calculation of the correlation of SPR angle shift response with the gold nanorod longitudinal absorbance bands. For nanospheres and nanooctahedrons, the SPR angle shift responses were found to be particle shape and size dependent in a simple way with a sustaining increase when the sizes of the nanoparticles were increased. Consequently, a guideline for choosing gold nanoparticles as tags is suggested for the SPR determination of small molecules with binding to the immobilized interaction partners.     

Spectral Tuning of Plasmon Resonances of Bimetallic Noble Metal Alloy Nanoparticles Through Compositional Changes

The optical absorption properties of the bimetallic noble metal alloy (viz. Au-Ag, Au-Cu, and Ag-Cu) nanoparticles (NPs) of radii of 10 nm and 20 nm embedded in silica glass have been studied theoretically using a simple model based on the effective medium theory. Our study reveals that the spectra of the above bimetallic alloy NPs exhibit single but composition-sensitive surface plasmon resonance (SPR) peak which indicates the successful formation of alloys. The position of the SPR peak that appeared corresponding to alloy NPs is different from that of the component metals. The study further reveals that the Ag-Au and Au-Cu alloy systems are completely miscible over the entire concentration range but Ag-Cu is miscible up to a certain extent, although, their SPR peak shows a linear shift with molar concentration. It has been further observed that the phase of the Ag-Au alloy system changes with concentration of Au during the alloy formation but no such change is seen in the other two systems. Thus, our study shows that the Ag-Cu system which otherwise does not form alloy in bulk may form alloy in nanoscale with limited miscibility. A shift of the SPR peak positions from ~ 405 to ~ 535 nm for Au-Ag, from ~ 535 to ~ 590 nm for Au-Cu, and from ~ 405 to ~ 436 nm for Ag-Cu NP systems has been observed for different composition of constituent monometals. The compositional changes lead to a spectral tuning of the SPR of the system under studies.

     

Tuning Plasmonic Properties of Truncated Gold Nanospheres by Coating

The influence of TiO₂ coating on resonant properties of gold nanoisland films deposited on silica substrates was studied numerically and in experiments. The model describing plasmonic properties of a metal truncated nanosphere placed on a substrate and covered by a thin dielectric layer has been developed. The model allows calculating a particle polarizability spectrum and, respectively, its surface plasmon resonance (SPR) wavelength for any given cover thickness, particle radius and truncation parameter, and dielectric functions of the particle, the substrate, the coating layer, and the surrounding medium. Dependence of the SPR position calculated for truncated gold nanospheres has coincided with the measured one for the gold nanoisland films covered with titania of different thicknesses. In the experiments, gold films with thickness of 5 nm were deposited on a silica glass substrate, annealed at 500 °C to form nanoislands of 20 nm in diameter, and covered with amorphous titania layers using atomic layer deposition technique. The resulting structures were characterized with scanning electron microscopy and optical absorption spectroscopy. The measured dependence of the SPR position on titania film thickness corresponded to the one calculated for truncated sphere-shaped nanoparticles with the truncation angle of ~50°. We demonstrated the possibility of tuning the SPR position within ~100 nm range by depositing to 30 nm thick titania layer.

     

Plasmonic Perfect Absorbers for Biosensing Applications

We present a theoretical modal investigation of plasmonic perfect absorbers (PPAs) based on the localized surface plasmon resonance (LSPR) for biosensing applications. We design the PPA geometry with a layer of periodic metallic nanoparticles on one side of a dielectric substrate and a single metallic layer on the opposite side. The electromagnetic (EM) fields confine partly in the surrounding medium above the substrate and within the substrate itself. We examine the modes of the PPA geometry for a wavelength range of 600–1500 nm. The fundamental mode of the system provides perfect absorption for a wide angle of incidence 0–70°. The second-order mode shows a strong angular dependence with a sharp resonance and exhibits perfect optical absorption when the critical coupling condition for LSPR is achieved. The coupling condition depends on the size, periodicity, dielectric spacer, and the surrounding material of the system. The strong dependence on the surrounding material makes it a promising candidate for biosensing applications. We introduce a novel approach to investigate the angular dependence of the refractive index change for the PPA system. This novel technique contributes the significant attributes of the LSPR sensors, can be used for any required resonance wavelength depending on geometric design, and it also provides sensitivity analogous to the standard surface plasmon resonance (SPR) biosensors.     

Plasmonic Broadband Polarization Splitter Based on Dual-Core Photonic Crystal Fiber with Elliptical Metallic Nanowires

We design two kinds of plasmonic broadband polarization splitters based on dual-core photonic crystal fiber (DC-PCF) with elliptical Au or Ag nanowire in this paper. It is analyzed for the polarization independent characterestics of the designed DC-PCF by the finite element method (FEM). In order to excite the surface plasmon resonance (SPR), the metal Au and Ag are filled into elliptical central air hole. The resonance coupling between the fourth- or fifth-order surface plasmon modes (SPMs) and core-guided modes (CGMs) are founded by this numerical simulation. The device lengths of the designed splitters with Au nanowire are 2937 and 827 μm at the wavelength of 1.31 and 1.55 μm, respectively. As the extinction ratios are better than ?20 dB, its bandwidths are better than 94 and 103 nm. For the designed Ag nanowire splitter, the device lengths are 3066 or 809 μm at 1.31 or 1.55 μm, respectively. The bandwidths with the extinction ratio better than ?20 dB are 66 and 104 nm, respectively.     

A Computational Study of the Giant Local Electric Field Enhancement in Al-Au-Ag Trimetallic Three-Layered Nanoshells

The surface plasmon resonance (SPR)-induced local field effect in Al-Au-Ag trimetallic three-layered nanoshells has been studied theoretically. Because of having three kinds of metal, three plasmonic bands have been observed in the absorption spectra and the local electric field factor spectra. The local electric field enhancement and the corresponding resonance wavelength for different plasmon coupling modes and spatial positions of the Al-Au-Ag nanoshells with various geometry dimensions are investigated to find the maximum local electric field enhancement. The calculation results indicate that the giant local electric field enhancement could be stimulated by the plasmon coupling in the middle Au shell or the outer Ag shell and could be optimized by increasing the Ag shell thickness and decreasing the Au shell thickness. What is more, the local electric field enhancement also nonmonotonously depends on the dielectric constant of the environment; the local electric field intensity will be weakened when the surrounding dielectric constant is too small or too large.

     

Plasmonic and Energy Studies of Ag Nanoparticles in Silica-Titania Hosts

The present work reports an investigation of surface plasmon resonance (SPR) of silver nanoparticles in SiO₂–TiO₂ hosts. The surface plasmon resonance of silver nanoparticles was observed in the wavelength range 300–400 nm. Numerical calculation of SPR of silver nanoparticles with spherical morphology was done on the basis of discrete dipole approximation (DDA) method. The observed fluorescence spectrum fits well with the theoretically calculated one. The luminescence enhancement is attributed to the strong local electric field which increases the exciting and emitting photons coupled to SPR. An effort has been made to study the surface plasmon mediated excitation energy transfer (EET) between two spherical metal nanoparticles. The van der Waals (vdW) energy between plasmonic silver nanoparticles in the present hosts has been estimated.     

Polarization Properties of Selectively Gold-filled Suspended Core Microstructured Optical Fibers

We study the polarization properties of suspended core microstructured optical fibers (SC-MOFs) with hexagonal lattice structure and high air-filling fraction having a single gold-filled hole along the horizontal axis. The interaction between the core-guided light and metal leads to surface plasmon resonance (SPR) at particular frequencies where the phase-matching condition is satisfied. We observe from the modal analysis that MOFs with high air-filling fraction offer the possibility of coupling of the fundamental mode with the first-order surface plasmon polariton (SPP) mode. With the increase in the suspension factor (SF), the fundamental mode couples with higher order SPP modes and the coupling strength also enhances. It also leads to an increase in modal birefringence. Reduction in beat length by an order of magnitude compared to the reported values is being reported for the first time to our knowledge. We have achieved the lowest beat length of 0.0105 mm at 1 μm wavelength for the structure having d/Λ = 0.85 and SF = 1.65. The results show that such plasmonic SC-MOFs may perform as efficient in-fiber polarizers and polarization filters.

     

Localized Surface Plasmon Resonance and Refractive Index Sensitivity of Metal–Dielectric–Metal Multilayered Nanostructures

The localized surface plasmon resonances of multilayered nanostructures are studied using finite difference time domain simulations and plasmon hybridization method. Concentric metal–dielectric–metal (MDM) structure with metal core and nanoshell separated by a thin dielectric layer exhibits a strong coupling between the core and nanoshell plasmon resonance modes. The coupled resonance mode wavelengths show dependence on the dielectric layer thickness and composition of core and outer layer metal. The aluminum-based MDM structures show lower plasmon wavelength compared with Ag- and Au-based MDM nanostructures. The calculated refractive index sensitivity (RIS) factor is in the order Ag–Air–Ag>Au–Air–Au>Al–Air–Al for monometallic multilayered nanostructures. Bimetallic multilayered nanostructures support strong and tunable plasmon resonance wavelengths as well as high RIS factor of 510 nm/refractive index unit (RIU) and 470 nm/RIU for Al–Air–Au and Ag-Air-Au, respectively. The MDM structures not only exhibit higher index sensitivity but also cover a wide ultraviolet–near-infrared wavelengths, making these structures very promising for index sensing, biomolecule sensing, and surface-enhanced Raman spectroscopy.     

Slab Thickness Dependence of Localized Surface Plasmon Resonance Behavior in Gold Nanorings

We present detailed experimental and numerical studies of plasmonic properties of gold nanoring (NR) arrays with different slab thicknesses from 15 to 125 nm. The hybrid plasmon resonances for the bonding and antibonding modes in gold NRs exhibit a high slab thickness dependence behavior in optical properties. For the thinner slab thickness below 50 nm, both hybrid modes show large spectral tunabilities by varying the slab thickness. Furthermore, for such hollow NR structure, the enhancements of electric field intensities at the inner and outer ring surfaces when reducing the slab thickness are investigated. We observe a significant transition of field distributions for the antibonding mode. All these features can be understood by surface charge distributions from our simulations. The results of this study offer a potential strategy to design a composite plasmonic nanostructure with large field enhancement for numerous applications.     

Surface Plasmon Resonance and Enhanced Fluorescence Application of Single-step Synthesized Elliptical Nano Gold-embedded Antimony Glass Dichroic Nanocomposites

A novel series of elliptical gold (Au⁰) nanoparticles (18–40 nm) embedded antimony glass (K₂O-B₂O₃-Sb₂O₃) dichroic nanocomposites have been synthesized by a single-step melt-quench in-situ thermochemical reduction technique. X-ray and selected area electron diffractions manifest growth of Au⁰ nanoparticles along the (111) and (200) crystallographic planes. The transmission electron microscopic image reveals elliptical Au⁰ nanoparticles having an aspect ratio varying in the range 1.2–2.1. The dichroic behavior of the nanocomposites arises due to elliptical shape of the Au⁰ nanoparticles. These nanocomposites show strong surface plasmon resonance (SPR) band of Au nanoparticles in the range 610–681 nm and it exhibit red-shifts with increasing Au concentration. They, when co-doped with Sm₂O₃ and excited at 949 nm, exhibit about sevenfold enhancement of the upconverted red emission transition of ⁴G_5/2→⁶H_9/2 at 636 nm due to local electric field enhancement effect of Au⁰ nanoparticles induced by its SPR. These nanocomposites are the promising materials for laser, display, and various nanophotonic applications.     

Determination of the Optical Thickness of sub 10-nm Thin Metal Films by SPR Experiments

We discuss the experimental data of surface plasmon resonance (SPR) occurring at the interface between air and single and bimetallic thin layers of Au and Ag prepared on glass substrates. The bilayer configuration allowed for the measurements of the optical constants of metallic films that are ultra thin; e.g., below 10 nm of thickness since SPR modes on such thin films in a single-layer configuration are shallow. We also discuss the effect of film thickness on SPR coupling. Thickness and refractive index of the films were determined by matching experimental SPR curves to the theoretical ones. Thickness and roughness of the films were also measured by atomic force microscopy. The results obtained by experimental measurements are in good agreement with AFM analysis.     

Review of Some Interesting Surface Plasmon Resonance-enhanced Properties of Noble Metal Nanoparticles and Their Applications to Biosystems

Noble metal, especially gold (Au) and silver (Ag) nanoparticles exhibit unique and tunable optical properties on account of their surface plasmon resonance (SPR). In this review, we discuss the SPR-enhanced optical properties of noble metal nanoparticles, with an emphasis on the recent advances in the utility of these plasmonic properties in molecular-specific imaging and sensing, photo-diagnostics, and selective photothermal therapy. The strongly enhanced SPR scattering from Au nanoparticles makes them useful as bright optical tags for molecular-specific biological imaging and detection using simple dark-field optical microscopy. On the other hand, the SPR absorption of the nanoparticles has allowed their use in the selective laser photothermal therapy of cancer. We also discuss the sensitivity of the nanoparticle SPR frequency to the local medium dielectric constant, which has been successfully exploited for the optical sensing of chemical and biological analytes. Plasmon coupling between metal nanoparticle pairs is also discussed, which forms the basis for nanoparticle assembly-based biodiagnostics and the plasmon ruler for dynamic measurement of nanoscale distances in biological systems.     

Highly Sensitive Plasmonic Refractive Index Sensor Based on Dual D-Shaped Photonic Crystal Fiber with Aluminum Nitride-Silver Films

A dual-core and dual D-shaped photonic crystal fiber (PCF)-based surface plasmon resonance (SPR) sensor with silver and aluminum nitride (AlN) films is designed. The distribution characteristics of the electromagnetic fields of core and plasmon modes, as well as the sensing properties, are numerically studied by finite element method (FEM). The structure parameters of the designed sensor are optimized by the optical loss spectrum. The results show the resonance wavelength variation of 489 nm for the refractive index (RI) range of 1.36?~?1.42. In addition, a maximum wavelength sensitivity of 13,400 nm/RIU with the corresponding RI resolution of 7.46?×?10^?6 RIU is obtained in the RI range of 1.41?~?1.42. The proposed sensor with the merits of high sensitivity, low cost, and simple structure has a wide application in the fields of RI sensing, such as hazardous gas detection, environmental monitoring, and biochemical analysis.