Recycle,Bury, or Burn Wood Waste Biomass?: LCA Answer Depends on Carbon Accounting,Emissions Controls,Displaced Fuels,and Impact Costs

This study extends existing life cycle assessment (LCA) literature by assessing seven environmental burdens and an overall monetized environmental score for eight recycle, bury, or burn options to manage clean wood wastes generated at construction and demolition activity sites. The study assesses direct environmental impacts along with substitution effects from displacing fossil fuels and managed forest wood sourcing activities. Follow‐on effects on forest carbon stocks, land use, and fuel markets are not assessed. Sensitivity analysis addresses landfill carbon storage and biodegradation rates, atmospheric emissions controls, displaced fuel types, and two alternative carbon accounting methods commonly used for waste management LCAs. Base‐case carbon accounting considers emissions and uptakes of all biogenic and fossil carbon compounds, including biogenic carbon dioxide. Base‐case results show that recycling options (recycling into reconstituted wood products or into wood pulp for papermaking) rank better than all burning or burying options for overall monetized score as well as for climate impacts, except that wood substitution for coal in industrial boilers is slightly better than recycling for the climate. Wood substitution for natural gas boiler fuel has the highest environmental impacts. Sensitivity analysis shows the overall monetized score rankings for recycling options to be robust except for the carbon accounting method, for which all options are highly sensitive. Under one of the alternative methods, wood substitution for coal boiler fuel and landfill options with high methane capture efficiency are the best for the overall score; recycling options are next to the worst. Under the other accounting alternative, wood substitution for coal and waste‐to‐energy are the best, followed by recycling options.     

Conventional and exergetic life cycle assessment of organic rankine cycle implementation to municipal waste management: the case study of Mae Hong Son (Thailand)

Purpose

The critical issue of waste management in Thailand has been rapidly increasing in almost all of the cities due to the economic growth and rising population that could double the amount of solid waste in landfill area. The alternative ways of waste treatment that have more efficiency and effectiveness in terms of energy, ecology, and resources become the key issue for each municipality to replace the old fashioned technology and be able to enhance the ability of solid waste problem management. Waste to energy is one of the favorable approaches to diminish the amount of waste to landfill and utilize waste for electricity. The aim of this study is to identify and quantify the life cycle impacts of the municipal solid waste (MSW) of Mae Hong Son municipality (MHSM), and the case study is the selected waste treatment technology of the Refuse-Derived Fuel (RDF) hybrid with 20 kW of Organic Rankine Cycle (ORC).

Methods

The functional unit is defined as 1 t of MSW. The energy, environment, and resource impacts were evaluated by using Life Cycle Assessment (LCA); ReCipe and Net Energy Consumption were referred to calculate the environmental impacts and the benefits of energy recovery of WtE technology. Exergetic LCA was used to analyze the resource consumption, especially land use change.

Results and discussion

The results indicated that the environmental impacts were comparatively high at the operation stage of RDF combustion. On the other hand, the production stage of RDF illustrated the highest energy consumption. The ORC power generation mainly consumed resources from material and energy used. The ORC system demonstrated better results in terms of energy and resource consumption when applied to waste management, especially the land required for landfill. Substitution of electricity production from ORC system was the contributor to the reduction of both energy and resource consumption. Installation of spray dry and fabric filter unit to RDF burner can reduce heavy metals and some pollutants leading to the reduction of most of the impacts such as climate change, human toxicity, and fossil depletion which are much lower than the conventional landfill.

Conclusions

LCA results revealed that the environmental impacts and energy consumption can be reduced by applying the RDF and ORC systems. The exergetic LCA is one of the appropriate tools used to evaluate the resource consumption of MSW. It is obviously proven that landfill contributed to higher impacts than WtE for waste management.

     

Could the recycled yarns substitute for the virgin cotton yarns: a comparative LCA

Purpose

Cotton yarns spun from natural fibers are widely used in the apparel industry. Most of waste cotton goods are now disposed by incineration or landfill, which brings resource and environmental challenges to the society. Using the waste cotton to spin yarns is an alternative way to forward a more sustainable future. In this research, two scenarios for the environmental impacts of yarns spun from corresponding fibers are investigated, including recycled cotton fibers and virgin cotton fibers.

Methods

The life cycle assessment (LCA) has been conducted according to the collected data from on-site investigation of typical production factories. The life cycle for the recycled cotton yarn production is divided into five stages, i.e., raw material acquisition, transportation, breaking, mixing, and spinning. The life cycle of virgin cotton yarn production is been divided into four stages, i.e., raw material acquisition, transportation, mixing, and spinning. The functional unit is 1000 kg produced yarns which are used for weaving into the fabrics. Notable impacts on climate change, fossil depletion, water depletion, and human toxicity were observed.

Results

The life cycle impact assessment (LCIA) results show that environmental impacts of recycled cotton yarns are far less than those of virgin cotton yarns, except for climate change and water depletion. The reason is that the land occupation and irrigation water have great impact on environmental impacts of cotton cultivation. In spinning, the electricity is the key factor whose environmental impacts account for the most in the virgin cotton yarn scenario, while the electricity and water consumptions are the key factors for the recycled cotton yarn scenario in the life cycle of yarn production. The sensitivity analysis indicates that improving energy efficiency can significantly reduce environmental burdens for both the two scenarios. The uncertainty distribution of water depletion, human toxicity, fossil depletion, and climate change of the two scenarios were determined with a 90% confidence interval.

Conclusions

The LCIA results reveal recycled cotton yarn is a viable alternative to relieve resource and environmental pressure. About 0.5 ha of agricultural land can be saved, 6600 kg CO₂ eq can be reduced, and 2783 m³ irrigation water can be saved by using 1000 kg of the recycled cotton yarns. It can be concluded that the recycled cotton fibers can be served as a substitute for virgin cotton fibers to reduce agricultural land and avoid environmental impacts generated from the cotton planting.

     

基于生命周期视角的产业资源生态管理效益分析——以虚拟共生网络系统为例

资源流代谢失调是造成产业生态环境问题的主要原因之一,对其实施基于共生网络的生态管理是解决问题的一项重要的举措。运用全生命周期的思想构建了产业资源共生网络及其管理框架,并运用全生命周期评价的方法,借助生命周期评价软件GaBi4,分别选取EI99 (Eco-Indicator 99)、CML2001 EP评价体系,以武汉市造纸产业为例,通过设计合理的资源流网络关系及中水、废纸和污泥利用共生路径构建虚拟造纸产业共生网络,对比分析了共生设计系统与原有共生系统的各生态环境影响。并运用市场价值法对共生设计系统的经济效益进行了分析。结果表明:共生设计系统总的环境影响、生态系统质量、人体健康、资源损耗值的环境影响分值分别为1166.445、814.509、148.893、203.045,比原有系统分别减少23.91%、19.15%、46.56%、22.26%;其中富营养化、气候变化的影响分别比原有系统降低56.25%、16.62%。同时共生设计系统通过污水、废纸及污泥的回用,在不考虑市场波动的情况下,可获得1018-7252万元的经济效益。可见,通过构建共生网络的生态管理是提高资源利用效率的有效手段之一,在一定条件下可取得明显的环境和经济效益。     

Accounting for transportation impacts in the environmental assessment of waste management plans

Background, aim, and scope  Many recent studies on waste management have described in detail the potential impacts of recycling and final treatment of municipal waste. In public debates, the attention has also been focused on the choice of final disposal technologies (e.g. landfilling vs. incineration). However, a comprehensive assessment of the impacts of waste collection and transport was still lacking. In the present study, we use LCA to evaluate the potential impact of the provincial waste management plan of Varese (northern Italy). Particular attention is devoted to the estimation of environmental impacts generated during waste transport. Materials and methods  A detailed Life Cycle Inventory was built for the transportation phase, based on primary data collected by interviewing the agencies involved in waste collection. To model the recycling and final disposal phase we relied on the BUWAL 250 database. Impacts were evaluated with the Eco-Indicator 99 method in its egalitarian formulation. Results  The results of our analysis reveal that the major potential impacts of the plan are associated with waste collection and transport. These impacts are partially compensated by reduced resource consumption through recycling and energy recovery through incineration. Discussion  The outputs of the LCIA were compared with those obtained by using other ecoindicators (Eco-Indicator 99 hierarchist and individualist, CML2, EPS2000). Although not comparable on a quantitative basis, they are qualitatively consistent. Conclusions  Neglecting the effects of collection and transport might result in a severe underestimation of the environmental impacts of a waste management system, especially as refers to depletion of fossil fuels, emission of respiratory inorganics and climate change. To reduce the environmental impact of waste management systems, an accurate optimisation of waste transport is required. Recommendations and perspectives  Effective waste management planning requires the explicit inclusion of waste collection and transport when comparing alternative management policies.     

A comparative life cycle assessment of two treatment technologies for the Grey Lanaset G textile dye: biodegradation by Trametes versicolor and granular activated carbon adsorption

Purpose

The aim of this study is to use life cycle assessment (LCA) to compare the relative environmental performance of the treatment using Trametes versicolor with a common method such as activated carbon adsorption. This comparison will evaluate potential environmental impacts of the two processes. This work compiles life cycle inventory data for a biological process that may be useful for other emergent biotechnological processes in water and waste management. LCA was performed to evaluate the use of a new technology for the removal of a model metal-complex dye, Grey Lanaset G, from textile wastewater by means of the fungus T. versicolor. This biological treatment was compared with a conventional coal-based activated carbon adsorption treatment to determine which alternative is preferable from an environmental point of view.

Materials and methods

The study is based on experimental research that has tested the novel process at the pilot scale. The analysis of the biological system ranges from the production of the electricity and ingredients required for the growth of the fungus and ends with the composting of the residual biomass from the process. The analysis of the activated carbon system includes the production of the adsorbent material and the electricity needed for the treatment and regeneration of the spent activated carbon. Seven indicators that measure the environmental performance of these technologies are included in the LCA. The indicators used are climate change, ozone depletion, human toxicity, photochemical oxidant formation, terrestial acidification, freshwater eutrophication, marine eutrophication, terrestrial ecotoxicity, freshwater ecotoxicity, marine ecotoxicity, metal depletion and fossil depletion.

Results

The results show that the energy use throughout the biological process, mainly for sterilisation and aeration, accounts for the major environmental impacts with the inoculum sterilisation being the most critical determinant. Nevertheless, the biological treatment has lower impacts than the physicochemical system in six of these indicators when steam is generated directly on site. A low-grade carbon source as an alternative to glucose might contribute to reduce the eutrophication impact of this process.

Conclusions

The LCA shows that the biological treatment process using the fungus T. versicolor to remove Grey Lanaset G offers important environmental advantages in comparison with the traditional activated carbon adsorption method. This study also provides environmental data and an indication of the potential impacts of characteristic processes that may be of interest for other applications in the field of biological waste treatment and wastewater treatment involving white-rot fungi.     

Significance of the use of non-renewable fossil CED as proxy indicator for screening LCA in the beverage packaging sector

Purpose

This study discusses the significance of the use of non-renewable fossil cumulative energy demand (CED) as proxy indicator in the beverage packaging sector, in order to detect those situations in which companies can benefit from the use of proxy indicators before a full life cycle assessment (LCA) application. Starting from a case study of two milk containers, the objectives of this paper are to assess if the use of this inventory indicator can be a suitable proxy indicator both (1) to decide which is the packaging alternative with the lowest environmental impact and (2) to identify the most impacting process units of the two products under study.

Method

The analysis was made according to ISO14040-44. The goal of the comparative LCA was to evaluate and to compare the potential environmental impacts from cradle to grave of a laminated carton container and a HDPE bottle. The results of the comparative LCA obtained with the non-renewable CED indicator are compared with a selection of impact categories: climate change, particulate matter formation, terrestrial acidification, fossil depletion, photochemical oxidant formation. A further analysis is made for the two products under study in order to determine which are the environmental hot spots in terms of life cycle stages, by the means of a contribution analysis.

Results and discussion

From the comparative LCA, the use of non-renewable CED revealed to be useful for a screening as the results given by the non-renewable CED indicator are confirmed by all the impact categories considered, even if underestimated. If the aim of the LCA study was to define which is the packaging solution with a lower environmental impact, the choice of this inventory indicator could have led to the same decision as if a comprehensive LCIA method was used. The contribution analysis, focusing on the identification of environmental hot spots in the packaging value chain, revealed that the choice of an inventory indicator as non-renewable CED can lead to misleading results, if compared with another impact category, such as climate change.

Conclusions

As in the future development of beverage packaging system, LCA will be necessarily integrated in the design process, it is important to define other ways of simplifying its application and spread its use among companies. The LCI indicator non-renewable fossil CED can effectively be used in order to obtain a preliminary estimation of the life cycle environmental impacts of two or more competing products in the beverage packaging sector.     

A diagnostic model for green productivity assessment of manufacturing processes

Goal, Scope and Background  Green Productivity (GP) is a new paradigm in sustainable manufacturing where resource conservation and waste minimization constitute the strategy in simultaneously enhancing environmental performance and productivity. This productivity approach to the sustainability of industries requires the adoption of clean production technology and the development of appropriate indicators and instruments to measure environmental performance in a continuous improvement strategy that focuses on the manufacturing stage of the product life cycle. The analysis may be expanded to include the entire life cycle with increasing details on impacts, improvement strategies and indicators. Methods  The study proposes a methodology for GP assessment that integrates the essential components of life cycle assessment (LCA) and multicriteria decision analysis specifically the analytic hierarchy process (AHP). LCA provides a systematic and holistic perspective for GP analysis that spans inventory, impact and improvement assessment. The AHP is utilized as a decision framework and valuation tool for impact and improvement assessment to come up with priority weights. Indicators are derived and measured from a streamlined LCA focused on a number of parameters within the gate-to-gate analysis to demonstrate the GP concept in relation to resource utilization and waste minimization. An input-output approach using a suitable material balance in a scenario analysis provides the basis of GP performance measurement. Results and Conclusion  The diagnostic model is applied on a semiconductor assembly/packaging operation. From the streamlined life cycle inventory, impact factors were derived for water resource depletion (WRD), energy resource depletion (ERD), human toxicity-air (HTA), human toxicity-land (HTL), human toxicity-water (HTW), aquatic ecotoxicity (ETA) and terrestrial ecotoxicity (ETT). Valuation of impact factors using the AHP showed the high significance of ETT, HTL, WRD and ERD. This especially reflects the impact of the industry on the solid waste problem as a result of emissions to land associated with human toxicity and ecotoxicity effects and the intensive use of water and energy resources. Using scenario analysis, the effect of implementing a process-based improvement technique on a product-specific operation was determined and the highest values in GP are for energy utilization, water utilization and terrestrial ecotoxicity. Recommendation and Perspective  Expert system technology was explored in developing a diagnostic prototype that emulates how human experts diagnose green productivity of manufacturing processes. The aim was to investigate how such a diagnosis could be performed in an intelligent fashion that it is also easily accessible as a decision support for industries. The expert system model will provide flexibility in testing the relationships of environmental performance and productivity parameters as well as in preserving and disseminating valuable human expertise in GP program implementation. This is a continuing research effort that is building the knowledge base for GP assessment. It will include case studies over a wider range or level of detail regarding the impacts and improvement techniques and the other stages of the product life cycle.     

Let's Be Clear(er) about Substitution: A Reporting Framework to Account for Product Displacement in Life Cycle Assessment

The multifunctional character of resource recovery in waste management systems is commonly addressed through system expansion/substitution in life cycle assessment (LCA). Avoided burdens credited based on expected displacement of other product systems can dominate the overall results, making the underlying assumptions particularly important for the interpretation and recommendations. Substitution modeling, however, is often poorly motivated or inadequately described, which limits the utility and comparability of such LCA studies. The aim of this study is therefore to provide a structure for the systematic reporting of information and assumptions expected to contribute to the substitution potential in order to make substitution modeling and the results thereof more transparent and interpretable. We propose a reporting framework that can also support the systematic estimation of substitution potentials related to resource recovery. Key components of the framework include waste‐specific (physical) resource potential, recovery efficiency, and displacement rate. End‐use–specific displacement rates can be derived as the product of the relative functionality (substitutability) of the recovered resources compared to potentially displaced products and the expected change in consumption of competing products. Substitutability can be determined based on technical functionality and can include additional constraints. The case of anaerobic digestion of organic household waste illustrates its application. The proposed framework enables well‐motivated substitution potentials to be accounted for, regardless of the chosen approach, and improves the reproducibility of comparative LCA studies of resource recovery.     

Insights on the Use of Hybrid Life Cycle Assessment for Environmental Footprinting

Establishing a comprehensive environmental footprint that indicates resource use and environmental release hotspots in both direct and indirect operations can help companies formulate impact reduction strategies as part of overall sustainability efforts. Life cycle assessment (LCA) is a useful approach for achieving these objectives. For most companies, financial data are more readily available than material and energy quantities, which suggests a hybrid LCA approach that emphasizes use of economic input‐output (EIO) LCA and process‐based energy and material flow models to frame and develop life cycle emission inventories resulting from company activities. We apply a hybrid LCA framework to an inland marine transportation company that transports bulk commodities within the United States. The analysis focuses on global warming potential, acidification, particulate matter emissions, eutrophication, ozone depletion, and water use. The results show that emissions of greenhouse gases, sulfur, and particulate matter are mainly from direct activities but that supply chain impacts are also significant, particularly in terms of water use. Hotspots were identified in the production, distribution, and use of fuel; the manufacturing, maintenance, and repair of boats and barges; food production; personnel air transport; and solid waste disposal. Results from the case study demonstrate that the aforementioned footprinting framework can provide a sufficiently reliable and comprehensive baseline for a company to formulate, measure, and monitor its efforts to reduce environmental impacts from internal and supply chain operations.     

Hierarchical Activity Model for Risk‐Based Decision Making

For the practical implementation of the assessment of environmental impact, actual procedures and data requirements should be clarified so that industrial decision makers understand them. Researchers should consider local risks related to processes and environmental impact throughout the life cycle of products simultaneously to supervise these adverse effects appropriately. Life cycle assessment (LCA) is a useful tool for quantifying the potential impact associated with a product life cycle. Risk assessment (RA) is a widely used tool for identifying chemical risks in a specific situation. In this study, we integrate LCA and RA for risk‐based decision making by devising a hierarchical activity model using the type‐zero method of integrated definition language (IDEF0). The IDEF0 activity modeling language has been applied to connect activities with information flows. Process generation, evaluation, and decision making are logically defined and visualized in the activity model with the required information. The activities, information flows, and their acquisitions are revealed, with a focus on which data should be collected by on‐site engineers. A case study is conducted on designing a metal cleaning process reducing chemical risks due to the use of a cleansing agent. LCA and RA are executed and applied effectively on the basis of integrated objective settings and interpretation. The proposed activity model can be used as a foundation to incorporate such assessments into actual business models.     

Using LCA to Assess Eco-design in the Automotive Sector: Case Study of a Polyolefinic Door Panel (12 pp)

Goal, Scope and Background The new European legislation concerning End-of-Life Vehicles (ELVs) will allow, in 2015, the landfilling of only 5% of the average vehicle weight, which means that the automotive industry must make a great effort in order to design their products taking into account their recyclability when they become waste. In the present work, LCA is used to assess an existing automotive component, a plastic door panel, and to compare it with a designed-for-recycling prototype panel, based on compatible polyolefins. Main Features A \\\'cradle to grave\\\' LCA is carried out for the panel currently produced and the prototype. The following scenarios are analyzed for plastic waste: landfilling (current practice in Spain), energy recovery in a MSW incinerator or in a cement kiln, and mechanical recycling. Results and Discussion The production and use phases together contribute more than 95% in most impact indicators. When the current and prototype products are compared, a decrease in the environmental impact appears for the prototype in the production phase and also at end-of-life if recycling is considered with full substitution of virgin polymers. The overall impact reduction ranges from 18% in the toxicity indicators to 80% in landfill use. Energy recovery in cement kilns appears as a good alternative to recycling in some indicators, such as landfill use or resource depletion. A sensitivity analysis is performed on the quality of recycled plastic, and the results suggest that the benefits of recycling are substantially reduced if full substitution is not achieved. Conclusion LCA has been shown to be a very useful tool to validate from an environmental point of view a redesigned automotive component; in addition, it has allowed one to identify not only the benefits from increased recyclability, but also improvements in other life cycle phases which were not previously expected. Recommendation and Perspective From this case study several recommendations to the company have been drawn in order to design environmentally friendly components for car interiors, and ecodesign is expected to be introduced in the company procedures. - Glossary ABS: Acrilonitrile-butadiene-styrene; ASR: Automobile shredder residue; DEHP: Di(ethylhexyl)phtalate; ELV: End-of-life vehicles; EPDM: Ethylene propylene diene monomer; MSW: Municipal solid waste; MSWI: Municipal solid waste incinerator; NEDC: New European driving cycle; PA GF: Polyamide glass fiber reinforced; PE: Polyethylene; PES: Polyester; POM: Polyoxymethylene; PP T16: Polypropylene 16% talc filled; PUR: Polyurethane; PVC: Polyvinyl chloride; TPO: Thermoplastic olefin     

From Grave to Cradle

Life cycle assessment (LCA) is a promising tool in the pursuit of sustainable mining. However, the accounting methodologies used in LCA for abiotic resource depletion still have some shortcomings and need to be improved. In this article a new thermodynamic approach is presented for the evaluation of the depletion of nonfuel minerals. The method is based on quantifying the exergy costs required to replace the extracted minerals with current available technologies, from a completely degraded state in what we term “Thanatia” to the conditions currently found in nature. Thanatia is an estimated reference model of a commercial end of the planet, where all resources have been extracted and dispersed, and all fossil fuels have been burned. Mineral deposits constitute an exergy bonus that nature gives us for free by providing minerals in a concentrated state and not dispersed in the crust. The exergy replacement costs provide a measure of the bonus lost through extraction. This approach allows performing an LCA by including a new stage in the analysis: namely the grave to cradle path. The methodology is explained through the case study of nickel depletion.     

The Application of the Environmental Product Declaration to Waste Disposal in a Sanitary Landfill - Four Case Studies (10 pp)

Goal, Scope and Background

The aim of the present study is to evaluate, through LCA, the potential environmental impact associated to urban waste dumping in a sanitary landfill for four case studies and to compare different technologies for waste treatment and leachate or biogas management in the framework of the EPD® system. Specific data were collected on the four Italian landfills during a five-year campaign from 2000 to 2004. This work also analyses the comparability of EPD results for different products in the same product category. For this purpose, a critical review of PSR 2003:3, for preparing an EPD on ‘Collection, transfer and disposal service for urban waste in sanitary landfills', is performed.

Methods

PSR 2003:3 defines the requirements, based on environmental parameters, that should be considered in an LCA study for collecting and disposal service of Municipal Solid Waste (MSW) in a sanitary landfill. It defines functional unit, system boundaries towards nature, other technical systems and boundaries in time, cut-off rules, allocation rules and parameters to be declared in the EPD. This PSR is tested on four case studies representing the major landfills located from the farthest west to the farthest east side of the Ligurian Region. Those landfills are managed with different technologies as concerns waste pre-treatment and leachate or biogas treatment. For each landfill, a life cycle assessment study is performed.

Results and Discussion

The comparison of the LCA results is performed separately for the following phases: Transport, Landfill, Leachate and Biogas. The following parameters are considered: Resource use (Use of non-renewable resources with and without energy content, Use of renewable resources with and without energy content, Water consumption); Pollutant emissions expressed as potential environmental impact (Global Warming Potential from biological and fossil sources, Acidification, Ozone depletion, Photochemical oxidant formation, Eutrophication, Land use, Hazardous and other Waste production). The comparison of the LCA results obtained for alternative landfill and biogas management techniques in the case studies investigated shows that the best practicable option that benefits the environment as a whole must be identified and chosen in the LCA context. For example, a strong waste pre-treatment causes a high biological GWP in the Landfill phase, but a low GWP contribution in the Biogas phase, due to the consequent low biogas production, evaluated for 30 years since landfill closure.

Conclusion

The analysis of four case studies showed that, through the EPD tool, it is possible to make a comparison among different declarations for the same product category only with some modification and integration to existent PSR 2003:3. Results showed that different products have different performances for phases and impact categories. It is not possible to identify the \best product\ from an environmental point of view, but it is possible to identify the product (or service) with the lowest impact on the environment for each impact category and resource use.

Recommendation and Perspective

In consequences of the verification of the comprehensiveness of existent PSR 2003:3 for the comparability of EPD, some modifications and integration to existent rules are suggested.

     

Life cycle assessment of a pyrolysis/gasification plant for hazardous paint waste

Goal, Scope and Background Life Cycle Assessment (LCA) remains an important tool in Dutch waste management policies. In 2002 the new National Waste Management Plan 2002–2012 (NWMP) became effective. It was supported by some 150 LCA studies for more than 20 different waste streams. The LCA results provided a benchmark level for new waste management technologies. Although not new, operational techniques using combined pyrolysis/gasification are still fairly rare in Europe. The goal of this study is to determine the environmental performance of the only full scale pyrolysis/gasification plant in the Netherlands and to compare it with more conventional techniques such as incineration. The results of the study support the process of obtaining environmental permits. Methods In this study we used an impact assessment method based on the guidelines described by the Centre of Environmental Science (CML) of Leiden University. The functional unit is defined as treatment of 1 ton of collected hazardous waste (paint packaging waste). Similar to the NWMP, not only normalized scores are presented but also 7 aggegated scores. All interventions from the foreground process (land use, emissions, final waste) are derived directly from the site with the exception of emissions to soil which were calculated. Interventions are accounted to each of the different waste streams by physical relations. Data from background processes are taken from the IVAM LCA database 4.0 mostly originating from the Swiss ETH96 database and adapted to the Dutch situation. Allocation was avoided by using system enlargement. The study has been peer reviewed by an external expert. Results and Discussion It was possible to determine an environmental performance for the pyrolysis/ gasification of paint packaging waste. The Life Cycle Inventory was mainly hampered by the uncertainty occurred with estimated air emissions. Here several assumptions had to be made because several waste inputs and two waste treatment installations profit from one flue gas cleaning treatment thus making it difficult to allocate the emission values from the flue gasses. Compared to incineration in a rotary kiln, pyrolysis/gasification of hazardous waste showed better scores for most of the considered impact categories. Only for the impact categories biodiversity and life support the incineration option proved favorable due to a lower land use. Several impact categories had significant influence on the conclusions: acidification, global warming potential, human toxicity and terrestrial ecotoxicity. The first three are related to a better energy efficiency for pyrolysis/gasification leading to less fossil energy consumption. Terrestrial ecotoxicity in this case is related to specific emissions of mercury and chromium (III). A sensitivity analysis has been performed as well. It was found that the environmental performance of the gasification technique is sensitive to the energy efficiency that can be reached as well as the choice for the avoided fossil energy source. In this study a conservative choice for diesel oil was made whereas a choice for heavy or light fuel oil would further improve the environmental profile. Conclusions Gasification of hazardous waste has a better environmental performance compared to the traditional incineration in rotary kilns mainly due to the high energy efficiency. As was determined by sensitivity analysis the differences in environmental performance are significant. Improvement options for a better performance are a decrease of process emissions (especially mercury) and a further improvement of the energy balance by decreasing the electricity consumption for shredders and oxygen consumption or making more use of green electricity. Recommendations and Perspectives Although the life cycle inventory was sufficiently complete, still some assumptions had to be made in order to establish sound mass balances on the level of individual components and substances. The data on input of waste and output of emissions and final waste were not compatible. It was recommended that companies put more emphasis on data storage accounted to particular waste streams. This is even more relevant since more companies in the future are expected to include life cycle impacts in their environmental performance.     

Extended Life Cycle Assessment of Southern Pink Shrimp Products Originating in Senegalese Artisanal and Industrial Fisheries for Export to Europe

Southern pink shrimp (Penaeus notialis) are an important Senegalese export commodity. Artisanal fisheries in rivers produce 60%. Forty percent are landed in trawl fisheries at sea. The shrimp from both fisheries result in a frozen, consumer‐packed product that is exported to Europe. We applied attributional life cycle assessment (LCA) to compare the environmental impact of the two supply chains and identify improvement options. In addition to standard LCA impact categories, biological impacts of each fishery were quantified with regard to landed by‐catch, discard, seafloor impact, and size of target catch. Results for typical LCA categories include that artisanal fisheries have much lower inputs and emissions in the fishing phase than does the industrial fishery. For the product from artisanal fisheries, the main part of the impact in the standard LCA categories occurs during processing on land, mainly due to the use of heavy fuel oil and refrigerants with high global warming and ozone depletion potentials. From a biological point of view, each fishery has advantages and drawbacks, and a number of improvement options were identified. If developing countries can ensure biological sustainability of their fisheries and design the chain on land in a resource‐efficient way, long distance to markets is not an obstacle to sustainable trading of seafood products originating in artisanal fisheries.     

Absolute versus Relative Environmental Sustainability

The cradle‐to‐cradle (C2C) concept has emerged as an alternative to the more established eco‐efficiency concept based on life cycle assessment (LCA). The two concepts differ fundamentally in that eco‐efficiency aims to reduce the negative environmental footprint of human activities while C2C attempts to increase the positive footprint. This article discusses the strengths and weaknesses of each concept and suggests how they may learn from each other. The eco‐efficiency concept involves no long‐term vision or strategy, the links between resource consumption and waste emissions are not well related to the sustainability state, and increases in eco‐efficiency may lead to increases in consumption levels and hence overall impact. The C2C concept's disregard for energy efficiency means that many current C2C products will likely not perform well in an LCA. Inherent drawbacks are restrictions on the development of new materials posed by the ambition of continuous loop recycling, the perception that human interactions with nature can benefit all parts of all ecosystems, and the hinted compatibility with continued economic growth. Practitioners of eco‐efficiency can benefit from the visions of C2C to avoid a narrow‐minded focus on the eco‐efficiency of products that are inherently unsustainable. Moreover, resource efficiency and positive environmental effects could be included more strongly in LCA. Practitioners of C2C on the other hand should recognize the value of LCA in addressing trade‐offs between resource conservation and energy use. Also, when designing a “healthy emission” it should be recognized that it will often have an adverse effect on parts of the exposed ecosystem.     

Land use indicators in life cycle assessment

Purpose  

Inclusion of land use-related environmental aspects into LCA methodology has been under active development in recent years. Although many indicators have been developed and proposed for different aspects of land use (climate change, biodiversity, resource depletion and soil quality), many of indicators have, as yet, not been tested and compared in LCA applications. The aim of this study is to test the different LCIA indicators in practice in a case study of beer production.     

Environmental hotspots of lactic acid production systems

Using selected bio‐based feedstocks as alternative to fossil resources for producing biochemicals and derived materials is increasingly considered an important goal of a viable bioeconomy worldwide. However, to ensure that using bio‐based feedstocks is aligned with the global sustainability agenda, impacts along the entire life cycle of biochemical production systems need to be evaluated. This will help to identify those processes and technologies, which should be targeted for optimizing overall environmental sustainability performance. To address this need, we quantify environmental impacts of biochemical production using distinct bio‐based feedstocks, and discuss the potential for reducing impact hotspots via process optimization. Lactic acid (LA) was used as an example biochemical derived from corn, corn stover, and macroalgae (Laminaria sp.) as feedstocks of different technological maturity. We used environmental life cycle assessment (LCA), a standardized methodology, considering the full life cycle of the analyzed biochemical production systems and a broad range of environmental impact indicators. Across production systems, feedstock production and biorefinery processes dominate life cycle impact profiles, with choice in energy mix and biomass processing as main influencing aspects. Results show that uncertainty decreases with increasing technological maturity. When using Laminaria sp. (least mature among selected feedstocks), impacts are mainly driven by energy utilities (up to 86%) due to biomass drying. This suggests to focus on optimizing or avoiding this process for significantly increasing environmental sustainability of Laminaria sp.‐based LA production. Our results demonstrate that applying LCA is useful for identifying environmental impact hotspots at an earlier stage of technological development across biochemical production systems. With that, our approach contributes to improving the environmental sustainability of future biochemical production as part of moving toward a viable bioeconomy worldwide.