共查询到20条相似文献,搜索用时 54 毫秒
1.
Seoung‐Bum Son James E. Trevey Hyunchul Roh Sung‐Hwan Kim Kee‐Bum Kim Jong Soo Cho Jeong‐Tak Moon Christopher M. DeLuca Kurt K. Maute Martin L. Dunn Heung Nam Han Kyu Hwan Oh Se‐Hee Lee 《Liver Transplantation》2011,1(6):1199-1204
We report the direct observation of microstructural changes of LixSi electrode with lithium insertion. HRTEM experiments confirm that lithiated amorphous silicon forms a shell around a core made up of the unlithiated silicon and that fully lithiated silicon contains a large number of pores of which concentration increases toward the center of the particle. Chemomechanical modeling is employed in order to explain this mechanical degradation resulting from stresses in the LixSi particles with lithium insertion. Because lithiation‐induced volume expansion and pulverization are the key mechanical effects that plague the performance and lifetime of high‐capacity Si anodes in lithium‐ion batteries, our observations and chemomechanical simulation provide important mechanistic insight for the design of advanced battery materials. 相似文献
2.
Asymmetric Rate Behavior of Si Anodes for Lithium‐Ion Batteries: Ultrafast De‐Lithiation versus Sluggish Lithiation at High Current Densities 下载免费PDF全文
Juchuan Li Nancy J. Dudney Xingcheng Xiao Yang‐Tse Cheng Chengdu Liang Mark W. Verbrugge 《Liver Transplantation》2015,5(6)
The combined effect of lithium‐ion diffusion, potential‐concentration gradient, and stress plays a critical role in the rate capability and cycle life of Si‐based anodes of lithium‐ion batteries. In this work, Si nanofilm anodes are shown to exhibit an asymmetric rate performance: around 72% of the total available capacity can be delivered during de‐lithiation under a high current density of 420 A g‐1 (100C where C is the charge‐rate) in 22 s; in striking contrast, only 1% capacity can be delivered during lithiation. A mathematical model of single‐ion diffusion is established to elucidate the asymmetric rate performance, which can be mainly attributed to the potential‐concentration profile associated with the active material and the ohmic voltage shift under high currents; the difference in chemical diffusion coefficients during lithiation and de‐lithiation also plays a role. This clarifies that the charge and discharge rates of lithium‐ion‐battery electrodes should be evaluated separately due to the asymmetric effect in the electrochemical system. 相似文献
3.
Yuwon Park Nam‐Soon Choi Sangjin Park Seung Hee Woo Soojin Sim Bo Yun Jang Seung M. Oh Soojin Park Jaephil Cho Kyu Tae Lee 《Liver Transplantation》2013,3(2):206-212
Remarkable improvements in the electrochemical performance of Si materials for Li‐ion batteries have been recently achieved, but the inherent volume change of Si still induces electrode expansion and external cell deformation. Here, the void structure in Si‐encapsulating hollow carbons is optimized in order to minimize the volume expansion of Si‐based anodes and improve electrochemical performance. When compared to chemical etching, the hollow structure is achieved via electroless etching is more advanced due to the improved electrical contact between carbon and Si. Despite the very thick electrodes (30 ~ 40 μm), this results in better cycle and rate performances including little capacity fading over 50 cycles and 1100 mA h g?1 at 2C rate. Also, an in situ dilatometer technique is used to perform a comprehensive study of electrode thickness change, and Si‐encapsulating hollow carbon mitigates the volume change of electrodes by adoption of void space, resulting in a small volume increase of 18% after full lithiation corresponding with a reversible capacity of about 2000 mA h g?1. 相似文献
4.
Stress‐Relieved Nanowires by Silicon Substitution for High‐Capacity and Stable Lithium Storage 下载免费PDF全文
Ting He Jianrui Feng Yan Zhang Lianhai Zu Guichang Wang Yan Yu Jinhu Yang 《Liver Transplantation》2018,8(14)
Silicon is promising as a high energy anode for next‐generation lithium‐ion batteries. However, severe capacity fading upon cycling associated with huge volume change is still an obstacle for silicon toward practical applications. Herein, the authors report that Si‐substituted Zn2(GeO4)0.8(SiO4)0.2 nanowires can effectively suppress volume expansion effect, exhibiting high specific capacity (1274 mA h g?1 at 0.2 A g?1 after 700 cycles) and ultralong cycling stability (2000 cycles at 5 A g?1 with a capacity decay rate of 0.008% per cycle), which represents outstanding comprehensive performance. The superior performance is ascribed to the substitution of Si atom that imparts to the nanowires not only high reactivity and reversibility, but also the unique stress‐relieved property upon lithiation which is further confirmed by detailed density‐functional theory computation. This work provides a new guideline for designing high‐performance Si‐based materials toward practical energy storage applications. 相似文献
5.
Ran Yi Fang Dai Mikhail L. Gordin Hiesang Sohn Donghai Wang 《Liver Transplantation》2013,3(11):1507-1515
Silicon has been intensively pursued as the most promising anode material for Li‐ion batteries due to its high theoretical capacity of 3579 mAh/g. Micro‐sized Si–C composites composed of nanoscale primary building blocks are attractive Si‐based anodes for practical application because they not only achieve excellent cycling stability, but also offer both gravimetric and volumetric capacity. However, the effects of key parameters in designing such materials on their electrochemical performance are unknown and how to optimize them thus remains to be explored. Herein, the influence of Si nanoscale building block size and carbon coating on the electrochemical performance of the micro‐sized Si–C composites is investigated. It is found that the critical Si building block size is 15 nm, which enables a high capacity without compromising the cycling stability, and that carbon coating at higher temperature improves the first cycle coulombic efficiency (CE) and the rate capability. Corresponding reasons underlying electrochemical performance are revealed by various characterizations. Combining both optimized Si building block size and carbon coating temperature, the resultant composite can sustain 600 cycles at 1.2 A/g with a fixed lithiation capacity of 1200 mAh/g, the best cycling performance with such a high capacity for micro‐sized Si‐based anodes. 相似文献
6.
Zeheng Li Yaping Zhang Tiefeng Liu Xuehui Gao Siyuan Li Min Ling Chengdu Liang Junchao Zheng Zhan Lin 《Liver Transplantation》2020,10(20)
High‐capacity electrode materials play a vital role for high‐energy‐density lithium‐ion batteries. Silicon (Si) has been regarded as a promising anode material because of its outstanding theoretical capacity, but it suffers from an inherent volume expansion problem. Binders have demonstrated improvements in the electrochemical performance of Si anodes. Achieving ultrahigh‐areal‐capacity Si anodes with rational binder strategies remains a significant challenge. Herein, a binder‐lithiated strategy is proposed for ultrahigh‐areal‐capacity Si anodes. A hard/soft modulated trifunctional network binder (N‐P‐LiPN) is constructed by the partially lithiated hard polyacrylic acid as a framework and partially lithiated soft Nafion as a buffer via the hydrogen binding effect. N‐P‐LiPN has strong adhesion and mechanical properties to accommodate huge volume change of the Si anode. In addition, lithium‐ions are transferred via the lithiated groups of N‐P‐LiPN, which significantly enhances the ionic conductivity of the Si anode. Hence, the Si@N‐P‐LiPN electrodes achieve the highest initial Coulombic efficiency of 93.18% and a stable cycling performance for 500 cycles at 0.2 C. Specially, Si@N‐P‐LiPN electrodes demonstrate an ultrahigh‐areal‐capacity of 49.59 mAh cm?2. This work offers a new approach for inspiring the battery community to explore novel binders for next‐generation high‐energy‐density storage devices. 相似文献
7.
One‐to‐One Comparison of Graphite‐Blended Negative Electrodes Using Silicon Nanolayer‐Embedded Graphite versus Commercial Benchmarking Materials for High‐Energy Lithium‐Ion Batteries 下载免费PDF全文
While existing carbonaceous anodes for lithium–ion batteries (LIBs) are approaching a practical capacitive limit, Si has been extensively examined as a potential alternative because it shows exceptional gravimetric capacity (3579 mA h g?1) and abundance. However, the actual implementation of Si anodes is impeded by difficulties in electrode calendering processes and requirements for excessive binding and conductive agents, arising from the brittleness, large volume expansion (>300%), and low electrical conductivity (1.56 × 10?3 S m?1) of Si. In one rational approach to using Si in high‐energy LIBs, mixing Si‐based materials with graphite has attracted attention as a feasible alternative for next‐generation anodes. In this study, graphite‐blended electrodes with Si nanolayer‐embedded graphite/carbon (G/SGC) are demonstrated and detailed one‐to‐one comparisons of these electrodes with industrially developed benchmarking samples are performed under the industrial electrode density (>1.6 g cc?1), areal capacity (>3 mA h cm?2), and a small amount of binder (3 wt%) in a slurry. Because of the favorable compatibility between SGC and conventional graphite, and the well‐established structural features of SGC, great potential is envisioned. Since this feasible study utilizes realistic test methods and criteria, the rigorous benchmarking comparison presents a comprehensive understanding for developing and characterizing Si‐based anodes for practicable high‐energy LIBs. 相似文献
8.
Jiyoung Ma Jaekyung Sung Yoonkwang Lee Yeonguk Son Sujong Chae Namhyung Kim Seong‐Hyeon Choi Jaephil Cho 《Liver Transplantation》2020,10(6)
To be a thinner and more lightweight lithium‐ion battery with high energy density, the next‐generation anode with high gravimetric and volumetric capacity is a prerequisite. In this regard, utilizing high silicon (3579 mAh g?1) content in the electrode for the anode has been highlighted as a practically relevant approach. However, there still remains a crucial issue related to intrinsic volume expansion (>300%) of silicon upon lithiation, which can directly affect severe electrode swelling as well as accelerate its capacity fading by triggering structural degradation and electrical contact loss between particles. Herein, macropore‐exploited design, which can accommodate the volume change of high silicon content within the extended pore of graphite upon repeated cycling, is introduced. Such unique macropore‐exploited design leads to much less electrode swelling, by preserving its morphological integrity and contact between particles, than that of the comparative group with different sized pore and silicon distribution. As a result, this anode (914 mAh g?1) demonstrates notable gravimetric (220 Wh kg?1 at 6000 W kg?1) and volumetric energy density (623 Wh L?1 upon full lithiation after 100 cycles), exceeding that of a nano‐silicon blended graphite anode (127 Wh kg?1 and 229 Wh L?1) in the full‐cell system. 相似文献
9.
Ultrahigh‐Energy‐Density Lithium‐Ion Batteries Based on a High‐Capacity Anode and a High‐Voltage Cathode with an Electroconductive Nanoparticle Shell 下载免费PDF全文
The combination of high‐capacity anodes and high‐voltage cathodes has garnered a great deal of attention in the pursuit of high‐energy‐density lithium‐ion batteries. As a facile and scalable electrode‐architecture strategy to achieve this goal, a direct one‐pot decoration of high‐capacity silicon (Si) anode materials and of high‐voltage LiCoO2 (LCO) cathode materials is demonstrated with colloidal nanoparticles composed of electroconductive antimony‐doped tin oxide (ATO). The unusual ATO nanoparticle shells enhance electronic conduction in the LCO and Si electrode materials and mitigate unwanted interfacial side reactions between the electrode materials and liquid electrolytes. The ATO‐coated LCO materials (ATO‐LCO) enable the construction of a high‐mass‐loading cathode and suppress the dissolution of cobalt and the generation of by‐products during high‐voltage cycling. In addition, the ATO‐coated Si (ATO‐Si) anodes exhibit highly stable capacity retention upon cycling. Integration of the high‐voltage ATO‐LCO cathode and high‐capacity ATO‐Si anode into a full cell configuration brings unprecedented improvements in the volumetric energy density and in the cycling performance compared to a commercialized cell system composed of LCO/graphite. 相似文献
10.
Si anodes suffer an inherent volume expansion problem. The consensus is that hydrogen bonds in these anodes are preferentially constructed between the binder and Si powder for enhanced adhesion and thus can improve cycling performance. There has been little research done in the field of understanding the contribution of the binder's mechanical properties to performance. Herein, a simple but effective strategy is proposed, combining hard/soft polymer systems, to exploit a robust binder with a 3D interpenetrating binding network (3D‐IBN) via an in situ polymerization. The 3D‐IBN structure is constructed by interweaving a hard poly(furfuryl alcohol) as the skeleton with a soft polyvinyl alcohol (PVA) as the filler, buffering the dramatic volume change of the Si anode. The resulting Si anode delivers an areal capacity of >10 mAh cm?2 and enables an energy density of >300 Wh kg?1 in a full lithium‐ion battery (LIB) cell. The component of the interweaving binder can be switched to other polymers, such as replacing PVA by thermoplastic polyurethane and styrene butadiene styrene. Such a strategy is also effective for other high‐capacity electroactive materials, e.g., Fe2O3 and Sn. This finding offers an alternative approach in designing high‐areal‐capacity electrodes through combined hard and soft polymer binders for high‐energy‐density LIBs. 相似文献
11.
In Operando Strain Measurement of Bicontinuous Silicon‐Coated Nickel Inverse Opal Anodes for Li‐Ion Batteries 下载免费PDF全文
Matthew P. B. Glazer Jiung Cho Jonathan Almer John Okasinski Paul V. Braun David C. Dunand 《Liver Transplantation》2015,5(14)
Elastic strains are measured in operando in a nanostructured silicon‐coated nickel inverse opal scaffold anode, using X‐ray diffraction to study the Si (de)lithiation‐induced Ni strains. The volume expansion upon lithiation of the Si in the anode is constrained by the surrounding Ni scaffold, causing mismatch stresses and strains in the Si and Ni phases during cycling. The Ni strains are measured in operando during (dis)charge cycles, using diffraction peak position and peak broadness to describe the distribution of strain in the Ni. During lithiation, compressive strains in the Ni first increase linearly with charge, after which a gradually decreasing strain rate is observed as the maximum lithiation state is approached; upon delithiation a similar process occurs. In‐plane average compressive strains on the order of 990 ± 40 με are measured in the Ni scaffold during lithiation, corresponding to compressive stresses of 215 ± 9 MPa. The decreasing strain rates and decreasing maximum and recovered strains suggest that plasticity in Ni and/or Si, as well as delamination between Ni and Si, may occur during cycling. Rate sensitivity in capacity is correlated with strain and a maximum Ni compressive stress of 230 ± 40 MPa is measured at the maximum state of lithiation. 相似文献
12.
Bing‐Qing Xiong Xinwei Zhou Gui‐Liang Xu Yuzi Liu Likun Zhu Youcheng Hu Shou‐Yu Shen Yu‐Hao Hong Si‐Cheng Wan Xiao‐Chen Liu Xiang Liu Shengli Chen Ling Huang Shi‐Gang Sun Khalil Amine Fu‐Sheng Ke 《Liver Transplantation》2020,10(4)
Alloy materials such as Si and Ge are attractive as high‐capacity anodes for rechargeable batteries, but such anodes undergo severe capacity degradation during discharge–charge processes. Compared to the over‐emphasized efforts on the electrode structure design to mitigate the volume changes, understanding and engineering of the solid‐electrolyte interphase (SEI) are significantly lacking. This work demonstrates that modifying the surface of alloy‐based anode materials by building an ultraconformal layer of Sb can significantly enhance their structural and interfacial stability during cycling. Combined experimental and theoretical studies consistently reveal that the ultraconformal Sb layer is dynamically converted to Li3Sb during cycling, which can selectively adsorb and catalytically decompose electrolyte additives to form a robust, thin, and dense LiF‐dominated SEI, and simultaneously restrain the decomposition of electrolyte solvents. Hence, the Sb‐coated porous Ge electrode delivers much higher initial Coulombic efficiency of 85% and higher reversible capacity of 1046 mAh g?1 after 200 cycles at 500 mA g?1, compared to only 72% and 170 mAh g?1 for bare porous Ge. The present finding has indicated that tailoring surface structures of electrode materials is an appealing approach to construct a robust SEI and achieve long‐term cycling stability for alloy‐based anode materials. 相似文献
13.
N‐Doped Graphene Modified 3D Porous Cu Current Collector toward Microscale Homogeneous Li Deposition for Li Metal Anodes 下载免费PDF全文
Rui Zhang Shuaiwei Wen Ning Wang Kaiqiang Qin Enzuo Liu Chunsheng Shi Naiqin Zhao 《Liver Transplantation》2018,8(23)
Lithium metal is the most promising anode material for high‐energy‐density batteries due to its high specific capacity of 3860 mAh g?1 and low reduction potential of ?3.04 V versus standard hydrogen electrode. However, huge volume change, safety concerns, and low efficiency impede the practical applications of Li metal anodes. Herein, it is shown that the nitrogen‐doped graphene modified 3D porous Cu (3DCu@NG) current collector can mitigate the above problems. The N‐doped graphene, coating on the surface of 3D current collector, not only contributes to a uniform Li+ flux, but also leads to a scattered distribution of electrons throughout the surface, finally contributing to a uniform Li deposition and the improved electrochemical performance. In addition, the continuously porous structure of 3DCu@NG provides a space for the metallic Li deposition and could effectually accommodate the volume expansion during cycling. As a result, the Li‐3DCu@NG anode exhibits a high areal capacity of 4 mAh cm?2, a high Li utilization of ≈98%, and an ultralow voltage hysteresis of ≈19 mV. The multifunctional N‐doped graphene modified 3D porous current collector promisingly provides a strategy for safe and high‐energy lithium metal anodes. 相似文献
14.
Yeonguk Son Jiyoung Ma Namhyung Kim Taeyong Lee Yoonkwang Lee Jaekyung Sung Seong‐Hyeon Choi Gyutae Nam Hyeyoung Cho Youngshin Yoo Jaephil Cho 《Liver Transplantation》2019,9(11)
Pseudocapacitive materials have been highlighted as promising electrode materials to overcome slow diffusion‐limited redox mechanism in active materials, which impedes fast charging/discharging in energy storage devices. However, previously reported pseudocapacitive properties have been rarely used in lithium‐ion batteries (LIBs) and evaluation methods have been limited to those focused on thin‐film‐type electrodes. Hence, a nanocage‐shaped silicon–carbon composite anode is proposed with excellent pseudocapacitive qualities for LIB applications. This composite anode exhibits a superior rate capability compared to other Si‐based anodes, including commercial silicon nanoparticles, because of the higher pseudocapacitive contribution coming from ultrathin Si layer. Furthermore, unprecedent 3D pore design in cage shape, which prevents the particle scale expansion even after full lithiation demonstrates the high cycling stability. This concept can potentially be used to realize high‐power and high‐energy LIB anode materials. 相似文献
15.
In Situ TEM Study of Volume Expansion in Porous Carbon Nanofiber/Sulfur Cathodes with Exceptional High‐Rate Performance 下载免费PDF全文
Zheng‐Long Xu Jian‐Qiu Huang Woon Gie Chong Xianying Qin Xiangyu Wang Limin Zhou Jang‐Kyo Kim 《Liver Transplantation》2017,7(9)
Although lithium sulfur batteries (LSBs) have attracted much interest owing to their high energy densities, synthesis of high‐rate cathodes and understanding their volume expansion behavior still remain challenging. Herein, electrospinning is used to prepare porous carbon nanofiber (PCNF) hosts, where both the pore volume and surface area are tailored by optimizing the sacrificial agent content and the activation temperature. Benefiting from the ameliorating functional features of high electrical conductivity, large pore volume, and Li ion permselective micropores, the PCNF/A550/S electrode activated at 550 °C exhibits a high sulfur loading of 71 wt%, a high capacity of 945 mA h g?1 at 1 C, and excellent high‐rate capability. The in situ transmission electron microscope examination reveals that the lithiation product, Li2S, is contained within the electrode with only ≈35% volume expansion and the carbon host remains intact without fracture. In contrast, the PCNF/A750/S electrode with damaged carbon spheres exhibits sulfur sublimation, a larger volume expansion of over 61%, and overflowing of Li2S, a testament to its poor cyclic stability. These findings provide, for the first time, a new insight into the correlation between volume expansion and electrochemical performance of the electrode, offering a potential design strategy to synthesize high‐rate and stable LSB cathodes. 相似文献
16.
A three‐dimensional porous core‐shell Sn@carbon anode on nickel foam substrate was fabricated by electrostatic spray deposition (ESD) technique followed by high temperature treatment. The carbon shell with a thickness of about 3.2 nm was formed on porous Sn structure at high temperature. 3D porous structure and carbon shell were designed to buffer volume expansion/shrinkage of Sn lattice upon cycling and increase the electrical conductivity. After 315 charge/discharge cycles Sn@carbon anode exhibited high specific capacity of 638 mAh g?1 with the low capacity fade of average 0.11 mAh g?1 per cycle. Sn@carbon based anodes was demonstrated to have promising potential for high performance lithium ion batteries application. 相似文献
17.
Xiao‐Yong Fan Jiaxing Han Yuan‐Li Ding Ya‐Ping Deng Dan Luo Xiangtian Zeng Zhen Jiang Lei Gou Dong‐Lin Li Zhongwei Chen 《Liver Transplantation》2019,9(28)
Alloying electrodes are regarded as promising anodes for lithium/sodium storage thanks to their multielectron reaction capacity, moderate voltage plateau, and high electrical conductivity. However, huge volume change upon cycling, especially for sodium storage, usually causes the loss of electrical connection between active components and their delaminations from traditional current collectors, thus leading to rapid capacity decay. Herein, a unique 3D current collector is assembled from 1D nanowire arrays anchored on 3D porous Cu foams for constructing core‐shelled Cu@Sb nanowires as advanced sodium‐ion battery (SIB) anodes. The so‐formed hierarchical 3D anode with interconnected 3D micrometer sized pores and abundant voids between nanowires not only effectively accommodates the structural strains during repeated cycling but also ensures the structural integrity and contributes to a uniform ion/electron scattered distribution throughout the whole surface. When employed as anodes for SIBs, the obtained electrode shows a high capacity of 605.3 mAh g?1 at 330 mA g?1, and demonstrates a high capacity retention of 84.8% even at a high current density of 3300 mA g?1. The 3D nanowire arrayed Cu current collector in this work can offer a promising strategy for designing and building advanced alloy anodes for lithium/sodium storage. 相似文献
18.
SiO2‐Enhanced Structural Stability and Strong Adhesion with a New Binder of Konjac Glucomannan Enables Stable Cycling of Silicon Anodes for Lithium‐Ion Batteries 下载免费PDF全文
Songtao Guo Heng Li Yaqian Li Yong Han Kebei Chen Gengzhao Xu Yingjie Zhu Xianluo Hu 《Liver Transplantation》2018,8(24)
Silicon‐based anodes with high theoretical capacity have intriguing potential applications for next‐generation high‐energy lithium‐ion batteries, but suffer from huge volumetric change that causes pulverization of electrodes. Rational design and construction of effective electrode structures combined with versatile binders remain a significant challenge. Here, a unique natural binder of konjac glucomannan (KGM) is developed and an amorphous protective layer of SiO2 is fabricated on the surface of Si nanoparticles (Si@SiO2) to enhance the adhesion. Benefiting from a plethora of hydroxyl groups, the KGM binder with inherently high adhesion and superior mechanical properties provides abundant contact sites to active materials. Molecular mechanics simulations and experimental results demonstrate that the enhanced adhesion between KGM and Si@SiO2 can bond the particles tightly to form a robust electrode. In addition to bridging KGM molecules, the SiO2‐functionalized surface may serve as a buffer layer to alleviate the stresses of Si nanoparticles resulting from the volume change. The as‐fabricated KGM/Si@SiO2 electrode exhibits outstanding structural stability upon long‐term cycles. A highly reversible capacity of 1278 mAh g?1 can be achieved over 1000 cycles at a current density of 2 A g?1, and the capacity decay is as small as 0.056% per cycle. 相似文献
19.
Best Practices for Mitigating Irreversible Capacity Loss of Negative Electrodes in Li‐Ion Batteries 下载免费PDF全文
Development of high performance lithium‐ion (Li‐ion) power packs is a topic receiving significant attention in research today. Future development of the Li‐ion power packs relies on the development of high capacity and high rate anodes. More specifically, materials undergo either conversion or an alloying mechanism with Li. However, irreversible capacity loss (ICL) is one of the prime issues for this type of negative electrode. Traditional insertion‐type materials also experience ICL, but it is considered negligible. Therefore, eliminating ICL is crucial before the fabrication of practical Li‐ion cells with conventional cathodes such as LiFePO4, LiMn2O4, etc. There are numerous methods for eliminating ICL such as pre‐treating the electrode, usage of stabilized Li metal powder, chemical and electrochemical lithiation, sacrificial salts for both anode and cathode, etc. The research strategies that have been explored are reviewed here in regards to the elimination of ICL from the high capacity anodes as described. Additionally, mitigating ICL observed from the carbonaceous anodes is discussed and compared. 相似文献
20.
Hung T. Nguyen Fei Yao Mihai R. Zamfir Chandan Biswas Kang Pyo So Young Hee Lee Seong Min Kim Seung Nam Cha Jong Min Kim Didier Pribat 《Liver Transplantation》2011,1(6):1154-1161
Silicon exhibits the largest known capacity for Li insertion in anodes of Li‐ion batteries. However, because of large volume expansion/phase changes upon alloying, Si becomes powder‐like after a few charge‐discharge cycles. Various approaches have been explored in the past to circumvent this problem, including the use of nanomaterials, particularly Si nanowires. However, even though nanowires resist cracking very well, anodes based on Si nanowires still see their original capacity fade away upon cycling, because of wire detachment from the substrate, due to the stress generated at their roots upon alloying with Li. Here, we present a silicon nanowire growth strategy yielding highly interconnected specimens, which prevents them from being individually detached from the substrate. We report a ~100% charge retention after 40 cycles at C/2 rate, without charging voltage limitation. We also show that our anodes can be cycled at 8C rates without damage and we grow nanowires with a density of 1.2 mg/cm2, yielding anodes delivering a 4.2 mAh/cm2 charge density. Finally, we point out that a better understanding of the interactions of silicon with electrolytes is needed if the field is to progress in the future. 相似文献