Low‐Overpotential Electrocatalytic Water Splitting with Noble‐Metal‐Free Nanoparticles Supported in a sp3 N‐Rich Flexible COF |
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| Authors: | Dinesh Mullangi Vishal Dhavale Sorout Shalini Shyamapada Nandi Sean Collins Tom Woo Sreekumar Kurungot Ramanathan Vaidhyanathan |
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| Affiliation: | 1. Department of Chemistry, Indian Institute of Science Education and Research, Pune, Maharashtra, India;2. Physical and Materials Chemistry Division, CSIR‐National Chemical Laboratory, Pune, Maharashtra, India;3. Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, Ottawa, Ontario, Canada;4. Centre for Energy Science, Indian Institute of Science Education and Research, Pune, India |
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| Abstract: | Covalent organic frameworks (COFs) are crystalline organic polymers with tunable structures. Here, a COF is prepared using building units with highly flexible tetrahedral sp3 nitrogens. This flexibility gives rise to structural changes which generate mesopores capable of confining very small (<2 nm sized) non‐noble‐metal‐based nanoparticles (NPs). This nanocomposite shows exceptional activity toward the oxygen‐evolution reaction from alkaline water with an overpotential of 258 mV at a current density of 10 mA cm?2. The overpotential observed in the COF‐nanoparticle system is the best in class, and is close to the current record of ≈200 mV for any noble‐metal‐free electrocatalytic water splitting system—the Fe–Co–Ni metal‐oxide‐film system. Also, it possesses outstanding kinetics (Tafel slope of 38.9 mV dec?1) for the reaction. The COF is able to stabilize such small‐sized NP in the absence of any capping agent because of the COF–Ni(OH)2 interactions arising from the N‐rich backbone of the COF. Density‐functional‐theory modeling of the interaction between the hexagonal Ni(OH)2 nanosheets and the COF shows that in the most favorable configuration the Ni(OH)2 nanosheets are sandwiched between the sp3 nitrogens of the adjacent COF layers and this can be crucial to maximizing their synergistic interactions. |
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| Keywords: | covalent organic frameworks non‐noble‐metal nanoparticles oxygen evolution reaction sp3‐nitrogen‐rich COFs water splitting |
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