Charge Generation and Recombination in an Organic Solar Cell with Low Energetic Offsets |
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| Authors: | Niva A. Ran John A. Love Michael C. Heiber Xuechen Jiao Michael P. Hughes Akchheta Karki Ming Wang Viktor V. Brus Hengbin Wang Dieter Neher Harald Ade Guillermo C. Bazan Thuc‐Quyen Nguyen |
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| Affiliation: | 1. Center for Polymers and Organic Solids, University of California, Santa Barbara, CA, USA;2. Institute of Physics and Astronomy, University of Potsdam, Potsdam, Germany;3. Department of Physics and Organic and Carbon Electronics Lab (ORaCEL), North Carolina State University, Raleigh, NC, USA;4. Helmholtz‐Zentrum Berlin für Materialien und Energie GmbH, Institut für Silizium Photovoltaik, Berlin, Germany;5. Mitsubishi Chemical Center for Advanced Materials, University of California, Santa Barbara, CA, USA |
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| Abstract: | Organic bulk heterojunction (BHJ) solar cells require energetic offsets between the donor and acceptor to obtain high short‐circuit currents (JSC) and fill factors (FF). However, it is necessary to reduce the energetic offsets to achieve high open‐circuit voltages (VOC). Recently, reports have highlighted BHJ blends that are pushing at the accepted limits of energetic offsets necessary for high efficiency. Unfortunately, most of these BHJs have modest FF values. How the energetic offset impacts the solar cell characteristics thus remains poorly understood. Here, a comprehensive characterization of the losses in a polymer:fullerene BHJ blend, PIPCP:phenyl‐C61‐butyric acid methyl ester (PC61BM), that achieves a high VOC (0.9 V) with very low energy losses (Eloss = 0.52 eV) from the energy of absorbed photons, a respectable JSC (13 mA cm?2), but a limited FF (54%) is reported. Despite the low energetic offset, the system does not suffer from field‐dependent generation and instead it is characterized by very fast nongeminate recombination and the presence of shallow traps. The charge‐carrier losses are attributed to suboptimal morphology due to high miscibility between PIPCP and PC61BM. These results hold promise that given the appropriate morphology, the JSC, VOC, and FF can all be improved, even with very low energetic offsets. |
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| Keywords: | energetic offset fill factor morphology organic solar cells recombination |
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