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The reaction of coumarins with horseradish peroxidase
Authors:Miller R W  Sirois J C  Morita H
Affiliation:Chemistry and Biology Research Institute and the Soil Research Institute, Research Branch, Agriculture Canada, Ottawa KIA OC6, Ontario, Canada.
Abstract:The peroxidase catalyzed oxidation of indole-3-acetate is inhibited by naturally occurring coumarins such as scopoletin. This inhibition is due to the preferential reactivity of the coumarins with the peroxidase compounds I, II, and III. In view of the possible growth regulatory role of coumarins in plants, the mechanism of oxidation of scopoletin by horse-radish peroxidase has been investigated.
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