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Microwave‐assisted sintering synthesis of greenish‐yellow emitting Sr2SiO4:Eu2+ phosphors
Authors:Woo Cheol Lee  Jin Young Park  Hyun Kyoung Yang  Minseok Kwak  Byung Kee Moon  Ki‐Wan Jang
Affiliation:1. Department of LED Convergence Engineering, Pukyong National University, Busan, Republic of Korea;2. Department of Chemistry, Pukyong National University, Busan, Republic of Korea;3. Department of Physics, Pukyong National University, Busan, Republic of Korea;4. Department of Physics, Changwon National University, Changwon, Republic of Korea
Abstract:Europium ion (Eu2+) doped Sr2SiO4 phosphors with greenish‐yellow emission were synthesized using microwave‐assisted sintering. The phase structure and photoluminescence (PL) properties of the obtained phosphor samples were investigated. The PL excitation spectra of the Sr2SiO4:Eu2+ phosphors exhibited a broad band in the range of 260 nm to 485 nm with a maximum at 361 nm attributed to the 5f‐4d allowed transition of the Eu2+ ions. Under an excitation at 361 nm, the Sr2SiO4:Eu2+ phosphor exhibited a greenish‐yellow emission peak at 541 nm with an International‐Commission‐on‐Illumination (CIE) chromaticity of (0.3064, 0.4772). The results suggest that the microwave‐assisted sintering method is promising for the synthesis of phosphors owing to the decreased sintering time without the use of additional reductive agents.
Keywords:microwave‐assisted sintering  phosphor  Sr2SiO4:Eu2+
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